The organic nitroxyl radical, TEMPO (2, 2, 6, 6-tetramethylpiperidine-N-oxyl), finds a variety
of industrial applications for chemical transformations. Because of economic and …

Persistent dialkylnitroxides (eg, 2, 2, 6, 6-tetramethylpiperidin-1-oxyl, TEMPO) play a central
role in the activity of hindered amine light stabilizers (HALS) additives that inhibit the …

The radical TEMPO and its derivatives find a variety of industrial applications as highly
selective oxidation catalysts for the production of pharmaceuticals, flavors and fragrances …

Nitroxyl radicals such as 2, 2, 6, 6-tetramethylpiperidine-1-oxyl (TEMPO) are highly selective
oxidation catalysts for the conversion of primary alcohols into the corresponding aldehydes …

We report a mild and efficient electrochemical protocol to access a variety of vicinally C–O
and C–N difunctionalized compounds from simple alkenes. Detailed mechanistic studies …

Visible light has risen to become a very important facilitator for selective radical reactions
enabled by well‐cognized photocatalysts. The renaissance of visible‐light photocatalysis on …

We report a novel coantioxidant system based on TEMPO (2, 2, 6, 6-tetramethylpiperidine-1-
oxyl radical) that, in biologically relevant model systems, rapidly converts chain-carrying …

TEMPO was readily grafted by copper (I)‐catalyzed azide‐alkyne cycloaddition onto
polystyrene. Starting with commercially available Merrifield resin (4.3 mmol/g) almost …

Nitroxides are a versatile class of stable free radicals that have long established themselves
in a wide range of applications. Their incorporation into macromolecular architectures has …

Disproportionation of TEMPO in acids leads to the formation of an N-oxoammonium salt,
which can further decompose under thermal conditions, yielding the corresponding …