Catalytic C− N bond formation by direct activation of C− H bonds offers wide synthetic
potential. En route to C− H amination, complexes with organic azides are critical precursors …

Formation of ubiquitous C–N bonds traditionally uses prefunctionalized carbon precursors.
Recently, metal-catalyzed amination of unfunctionalized C–H bonds with azides has …

Intramolecular aminations of C–H bonds represent an elegant synthetic way to form
important N-heterocycles. If suitable nitrene precursors are employed, organometallic …

The direct catalytic transformation of typically inert carbon–hydrogen bonds into carbon–
oxygen, carbon–nitrogen, and carbon–carbon bonds represents a significant challenge in …

Transition-metal-catalyzed direct C–N bond formation via metal nitrenoid (metal
imido/nitrene complexes) transfer reactions such as C–H bond amination/amidation and …

Conspectus Owing to the prevalence of nitrogen-containing compounds in functional
materials, natural products and important pharmaceutical agents, chemists have actively …

C–H amination reactions are valuable transformations for the construction of C–N bonds.
Due to their relatively high bond dissociation energies, C (sp2)–H bonds are generally not …

The discovery of transition metal complexes capable of promoting general, catalyst-
controlled and selective carbon–hydrogen (C–H) bond amination of activated secondary C …

The 7-coordinate complex [Fe (qpy)(MeCN) 2](ClO4) 2 (1, qpy= 2, 2′: 6′, 2 ″: 6 ″,
2′′′: 6′′′, 2′′′′-quinquepyridine) is a highly active nonheme iron catalyst for …

Transition‐metal‐catalyzed C—H bond amination reaction is an attractive method for the
synthesis of amines. Fueled by the growing interests in the development of economical and …