The five-coordinate iron (II) hydride complex (i PrPNP) Fe (H)(CO)(i PrPNP= N [CH2CH2 (P i
Pr2)] 2) selectively catalyzes the dehydrogenative intermolecular coupling of alcohols and …

It is challenging to develop simple and low cost catalytic systems while maintaining high
reactivity and selectivity. An iron-catalyzed intramolecular C–H amination of sulfamate esters …

The development of efficient and elective transition metal catalyst systems enabling a direct
C–H amination of hydrocarbons using ammonia is highly desirable considering the fact that …

C− H amination and amidation by catalytic nitrene transfer are well‐established and typically
proceed via electrophilic attack of nitrenoid intermediates. In contrast, the insertion of …

Conspectus Catalytic C–N bond cross-coupling reactions have been a subject of
fundamental importance in synthetic organic and medicinal chemistry because amides and …

Transition-metal-catalyzed C–H amination via nitrene insertion allows the direct
transformation of a C–H into a C–N bond. Given the ubiquity of C–H bonds in organic …

Much attention has been concentrated on metal-catalyzed atom and group transfers to
organic molecules as a strategy for carbon–heteroatom bond formation in synthetic organic …

N-Mesyloxycarbamates are practical nitrene precursors that undergo C–H amination
reactions in the presence of rhodium dimer catalysts. Under these conditions, both …

Cobalt complexes of amide-based pincers provide a hydrogen bonding pocket that is shown
to bind a reagent in the vicinity of a metal center. These cobalt complexes function as non …

The mechanisms and site-selective determinants of Rh2II, II (esp) 2-catalyzed intermolecular
C–H bond aminations of three isoamylbenzene-derived substrates, pR–C6H4 (CH2) 2CH …