Reaction chemistry and ligand exchange at cadmium− selenide nanocrystal surfaces
The surface chemistry of cadmium selenide nanocrystals, prepared from tri-n-
octylphosphine selenide and cadmium octadecylphosphonate in tri-n-octylphosphine oxide …
octylphosphine selenide and cadmium octadecylphosphonate in tri-n-octylphosphine oxide …
Size-dependent dissociation pH of thiolate ligands from cadmium chalcogenide nanocrystals
A method, pseudo steady-state titration, is introduced for determining the precipitation pH of
nanocrystals coated by electron-donating ligands. CdSe nanocrystals coated with …
nanocrystals coated by electron-donating ligands. CdSe nanocrystals coated with …
Quantifying ligand exchange reactions at CdSe nanocrystal surfaces
RR Knauf, JC Lennox, JL Dempsey - Chemistry of Materials, 2016 - ACS Publications
The exchange reactions of X-type ligands at the surface of CdSe nanocrystals have been
quantified via 1H NMR, absorbance, and emission spectroscopies. 1H NMR was used to …
quantified via 1H NMR, absorbance, and emission spectroscopies. 1H NMR was used to …
Tight binding of carboxylate, phosphonate, and carbamate anions to stoichiometric CdSe nanocrystals
PE Chen, NC Anderson, ZM Norman… - Journal of the American …, 2017 - ACS Publications
To completely displace the carboxylate surface ligands from cadmium selenide
nanocrystals, oleic acid impurities are first removed using dimethylcadmium or diethylzinc. In …
nanocrystals, oleic acid impurities are first removed using dimethylcadmium or diethylzinc. In …
Semiconductor nanocrystals covalently bound to metal surfaces with self-assembled monolayers
VL Colvin, AN Goldstein… - Journal of the American …, 1992 - ACS Publications
A method is described for attaching semiconductor nanocrystals to metalsurfaces using self-
assembled difunctional organic monolayers as bridge compounds. Three different …
assembled difunctional organic monolayers as bridge compounds. Three different …
Colloidal CdSe nanoplatelets, a model for surface chemistry/optoelectronic property relations in semiconductor nanocrystals
While the surface termination of quasi-spherical metal chalcogenide nanocrystals or
quantum dots has been widely investigated, it remains unclear whether the ensuing surface …
quantum dots has been widely investigated, it remains unclear whether the ensuing surface …
Stabilization of inorganic nanocrystals by organic dendrons
A series of hydrophilic organic dendron ligands was designed and synthesized for
stabilizing high-quality semiconductor and noble metal nanocrystals. The focal point of the …
stabilizing high-quality semiconductor and noble metal nanocrystals. The focal point of the …
Chelating ligands for nanocrystals' surface functionalization
A new family of ligands for the surface functionalization of CdSe nanocrystals is proposed,
namely alkyl or aryl derivatives of carbodithioic acids (R− C (S) SH). The main advantages of …
namely alkyl or aryl derivatives of carbodithioic acids (R− C (S) SH). The main advantages of …
Ligand exchange and the stoichiometry of metal chalcogenide nanocrystals: spectroscopic observation of facile metal-carboxylate displacement and binding
We demonstrate that metal carboxylate complexes (L–M (O2CR) 2, R= oleyl, tetradecyl, M=
Cd, Pb) are readily displaced from carboxylate-terminated ME nanocrystals (ME= CdSe …
Cd, Pb) are readily displaced from carboxylate-terminated ME nanocrystals (ME= CdSe …
Investigation of the surface morphology of capped CdSe nanocrystallites by 31P nuclear magnetic resonance
Room temperature 31 P magic angle sample spinning (MAS) nuclear magnetic resonance
(NMR) is used to study the phosphine chalconide species coordinating the surface of CdSe …
(NMR) is used to study the phosphine chalconide species coordinating the surface of CdSe …