Carboxylation of cellulose nanocrystals for reinforcing and toughing rubber through dual cross-linking networks

J Hu, Z Kong, K Liu, J Qin, Y Tao, L Zhou… - ACS Applied Polymer …, 2021 - ACS Publications
The surface functionalization of cellulose nanocrystals (CNCs) and the construction of strong
interfacial adhesion between CNCs and the rubber matrix are effective ways to achieve high …

Mechanical strong and recyclable rubber nanocomposites with sustainable cellulose nanocrystals and interfacial exchangeable bonds

L Cao, Z Gong, C Xu, Y Chen - ACS Sustainable Chemistry & …, 2021 - ACS Publications
Rubber is a strategically important polymeric material because of its high extensibility and
resilience. However, traditional cross-linked rubber is difficult to be reprocessed or recycled …

Dual cross-linked epoxidized natural rubber reinforced by tunicate cellulose nanocrystals with improved strength and extensibility

L Cao, J Huang, Y Chen - ACS sustainable chemistry & …, 2018 - ACS Publications
Cellulose nanocrystals have been proved to be ideal reinforcing fillers for rubber. However,
the increase in tensile strength always accompanies a reduction in extensibility. In this …

Covalent-bond-forming method to reinforce rubber with cellulose nanocrystal based on the thiol-ene click reaction

M Jiang, J Zhang, Y Wang, I Ahmad, X Guo… - Composites …, 2021 - Elsevier
Cellulose nanocrystals (CNCs) have been widely used in reinforcing polymers due to their
excellent mechanical properties, whereas the poor compatibility between CNCs and …

Biocomposites from natural rubber: Synergistic effects of functionalized cellulose nanocrystals as both reinforcing and cross-linking agents via free-radical thiol–ene …

B Parambath Kanoth, M Claudino… - … applied materials & …, 2015 - ACS Publications
Natural rubber/cellulose nanocrystals (NR/CNCs) form true biocomposites from renewable
resources and are demonstrated to show significantly improved thermo-mechanical …

Batch Mixing for the In Situ Grafting of Epoxidized Rubber onto Cellulose Nanocrystals

E Ojogbo, C Tzoganakis… - … Sustainable Chemistry & …, 2022 - ACS Publications
Cellulose nanocrystals (CNCs) are sustainable nanomaterials commonly employed as
biofillers in polymer composites. However, they disperse poorly in hydrophobic polymers in …

Effects of the surface chemical groups of cellulose nanocrystals on the vulcanization and mechanical properties of natural rubber/cellulose nanocrystals …

J Hu, H Wu, S Liang, X Tian, K Liu, M Jiang… - International Journal of …, 2023 - Elsevier
Cellulose nanocrystals (CNCs), as the promising reinforcing fillers in the rubber industry,
their surface chemical groups have vital effects on the vulcanization kinetics, cross-linking …

Synergistic reinforcing and cross-linking effect of thiol-ene-modified cellulose nanofibrils on natural rubber

G Zhu, A Dufresne - Carbohydrate Polymers, 2022 - Elsevier
To achieve synergistic reinforcing and cross-linking effect across interface between
hydrophilic nanocellulose and hydrophobic rubber, active thiol groups were introduced at …

The effect of sulfate half-ester groups on the mechanical performance of cellulose nanocrystal-natural rubber composites

IE Imiete, L Giannini, L Tadiello, M Orlandi, L Zoia - Cellulose, 2023 - Springer
Cellulose nanocrystals (CNCs) are commercially produced via hydrolysis by sulfuric acid,
resulting in the formation of sulfate half-ester groups on the surface of the nanoparticles. The …

Nanocrystalline cellulose isolated from different renewable sources to fabricate natural rubber composites with outstanding mechanical properties

W Jiang, J Gu - Cellulose, 2020 - Springer
Although nanocellulose has the advantages of rich source and high modulus, choosing a
good nanocellulose source and preparing high performance composites for industrial …