An adjacent atomic platinum site enables single‐atom iron with high oxygen reduction reaction performance

A Han, X Wang, K Tang, Z Zhang, C Ye… - Angewandte Chemie …, 2021 - Wiley Online Library
The modulation effect has been widely investigated to tune the electronic state of single‐
atomic M‐N‐C catalysts to enhance the activity of oxygen reduction reaction (ORR) …

Atomically Dispersed Fe–N3C Sites Induce Asymmetric Electron Structures to Afford Superior Oxygen Reduction Activity

M Tong, P Yu, Y Xie, L Wang, Y Wang, H Fu - Small, 2022 - Wiley Online Library
Introducing heteroatoms into atomically dispersed Fe–N4 sites with symmetric electron
distribution can adjust the imperfect oxygenated adsorption‐activation and promote oxygen …

Regulating the FeN4 Moiety by Constructing Fe–Mo Dual-Metal Atom Sites for Efficient Electrochemical Oxygen Reduction

P Zhu, X Xiong, X Wang, C Ye, J Li, W Sun, X Sun… - Nano Letters, 2022 - ACS Publications
An Fe–N–C catalyst with an FeN4 active moiety has gained ever-increasing attention for the
oxygen reduction reaction (ORR); however, the catalytic performance is sluggish in acidic …

Altering the spin state of Fe-NC through ligand field modulation of single-atom sites boosts the oxygen reduction reaction

D Xue, P Yuan, S Jiang, Y Wei, Y Zhou, CL Dong… - Nano Energy, 2023 - Elsevier
Atomically dispersed Fe-NC catalysts are the most promising candidates alternatively to Pt-
based catalysts for oxygen reduction reaction (ORR). However, the ORR activity of Fe-N x …

d‐Orbital Electron Delocalization Realized by Axial Fe4C Atomic Clusters Delivers High‐Performance Fe–N–C Catalysts for Oxygen Reduction Reaction

LJ Yuan, B Liu, L Shen, YK Dai, Q Li, C Liu… - Advanced …, 2023 - Wiley Online Library
Fe–N–C catalyst for oxygen reduction reaction (ORR) has been considered as the most
promising nonprecious metal catalyst due to its comparable catalytic performance to Pt in …

Unraveling the mechanism of ligands regulating electronic structure of MN4 sites with optimized ORR catalytic performance

B Li, H Xie, C Yang, C Shi, C He, N Zhao, E Liu - Applied Surface Science, 2022 - Elsevier
As an emerging platinum group metal-free material, metal-nitrogen-carbon (M− N− C)
catalysts are promising alternatives to Pt/C catalysts for the oxygen reduction reaction …

Engineering Energy Level of FeN4 Sites via Dual‐Atom Site Construction Toward Efficient Oxygen Reduction

Z Luo, X Li, T Zhou, Y Guan, J Luo, L Zhang, X Sun… - Small, 2023 - Wiley Online Library
Single‐atom catalysts based on metal–N4 moieties and embedded in a graphite matrix
(defined as M N C) are promising for oxygen reduction reaction (ORR). However, the …

Fe-based non-noble metal catalysts with dual active sites of nanosized metal carbide and single-atomic species for oxygen reduction reaction

GS Kang, JH Jang, SY Son, CH Lee, YK Lee… - Journal of Materials …, 2020 - pubs.rsc.org
Single-atom catalysts have been considered as representative non-noble metal catalysts for
replacing the platinum catalyst. Fundamentally, the dispersion of metal atoms on a carbon …

Synergies of Fe single atoms and clusters on N‐doped carbon electrocatalyst for pH‐universal oxygen reduction

M Liu, J Lee, TC Yang, F Zheng, J Zhao… - Small …, 2021 - Wiley Online Library
Single atomic metal–N–C materials have attracted immense interest as promising
candidates to replace noble metal‐based electrocatalysts for the oxygen reduction reaction …

Activating Single‐Atom Ni Site via First‐Shell Si Modulation Boosts Oxygen Reduction Reaction

F Wang, Y Li, R Zhang, H Liu, Y Zhang, X Zheng… - Small, 2023 - Wiley Online Library
Atomically dispersed nitrogen‐coordinated 3d transition‐metal site on carbon support (M‐
NC) are promising alternatives to Pt group metal‐based catalysts toward oxygen reduction …