High-valent metal-oxo species heterogeneous activation making use of MoS2 in a novel Electro-Fenton System: pH-independent catalytic environment and nonradical …

D Yu, J He, L Bai, Y Zheng, Z Wang, O Lefebvre… - Chemical Engineering …, 2024 - Elsevier
High-valent metal-oxo (HVMO) species emerge as promising reactive species for
decontamination owing to its long and stable life expectancy. Nevertheless, it is challenging …

Asymmetrically Coordinated CoB1N3 Moieties for Selective Generation of High‐Valence Co‐Oxo Species via Coupled Electron–Proton Transfer in Fenton‐like …

J Song, N Hou, X Liu, M Antonietti, P Zhang… - Advanced …, 2023 - Wiley Online Library
High‐valence metal species generated in peroxymonosulfate (PMS)‐based Fenton‐like
processes are promising candidates for selective degradation of contaminants in water, the …

Mechanistic insight into the heterogeneous electro-Fenton/sulfite process for ultraefficient degradation of pollutants over a wide pH range

G Song, M Zhou, X Du, P Su, J Guo - Acs Es&T Water, 2021 - ACS Publications
Electro-Fenton (EF) has received widespread attention in terms of water decontamination in
advanced oxidation processes but still has the bottlenecks of a narrow pH (∼ 3) application …

CoN1O2 Single‐Atom Catalyst for Efficient Peroxymonosulfate Activation and Selective Cobalt(IV)=O Generation

X Li, X Wen, J Lang, Y Wei, J Miao, X Zhang… - Angewandte …, 2023 - Wiley Online Library
High‐valent metal‐oxo (HVMO) species are powerful non‐radical reactive species that
enhance advanced oxidation processes (AOPs) due to their long half‐lives and high …

Toward Practical Water Decontaminations via Peroxymonosulfate Nonradical Oxidation: The Role of Cocatalyst MoS2 with Sulfur Vacancies

Z Li, Y Huo, T Li, S Dong, M Huo, G Liu… - ACS ES&T …, 2023 - ACS Publications
Molybdenum disulfide (MoS2) is a prevalent cocatalyst for peroxymonosulfate (PMS)
activation with iron-based materials. The contribution of molybdenum atoms in cocatalyst …

Bioinspired axial S-coordinated single-atom cobalt catalyst to efficient activate peroxymonosulfate for selective high-valent Co-Oxo species generation

C Gu, Y Zhang, P He, M Gan, J Zhu, H Yin - Journal of Hazardous Materials, 2024 - Elsevier
The efficient activation and selective high-valent metal-oxo (HVMO) species generation
remain challenging for peroxymonosulfate (PMS)-based advanced oxidation processes …

Boosting Hydroxyl Radical Yield via Synergistic Activation of Electrogenerated HOCl/H2O2 in Electro-Fenton-like Degradation of Contaminants under Chloride …

MR Haider, WL Jiang, JL Han… - Environmental …, 2023 - ACS Publications
Hydroxyl radical production via catalytic activation of HOCl is a new type of Fenton-like
process. However, metal–chlorocomplex formation under high chloride conditions could …

Oxygen Vacancy-Induced Nonradical Degradation of Organics: Critical Trigger of Oxygen (O2) in the Fe–Co LDH/Peroxymonosulfate System

L Wu, Z Sun, Y Zhen, S Zhu, C Yang, J Lu… - Environmental …, 2021 - ACS Publications
Ubiquitous oxygen vacancies (Vo) existing in metallic compounds can activate
peroxymonosulfate (PMS) for water treatment. However, under environmental conditions …

Self-assembly of MoS2 nanosheet adhered on Fe-MOF heterocrystals for peroxymonosulfate activation via interfacial interaction

L Zhang, B Zhang, L Wang, R Ge, W Zhou… - Journal of Colloid and …, 2022 - Elsevier
A novel heterogeneous catalyst PB@ MoS 2 was successfully synthesized via facile
hydrothermal processes and identified as a superior peroxymonosulfate (PMS) activator for …

Triggering of Low-Valence Molybdenum in Multiphasic MoS2 for Effective Reactive Oxygen Species Output in Catalytic Fenton-like Reactions

Y Chen, G Zhang, Q Ji, H Liu, J Qu - ACS applied materials & …, 2019 - ACS Publications
Utilization of photocatalytic reactions to trigger persistent large-scale reactions could be an
alternative path for practical solar energy conversion to relieve environmental pressure …