A Heteroleptic Gold Hydride Nanocluster for Efficient and Selective Electrocatalytic Reduction of CO2 to CO
It has been a long-standing challenge to create and identify the active sites of
heterogeneous catalysts, because it is difficult to precisely control the interfacial chemistry at …
heterogeneous catalysts, because it is difficult to precisely control the interfacial chemistry at …
Active sites of ligand-protected Au25 nanoparticle catalysts for CO2 electroreduction to CO
Recent experimental studies have reported the electrochemical reduction of carbon dioxide
(CO 2) into CO at atomically precise negatively charged Au 25− nanoclusters. The studies …
(CO 2) into CO at atomically precise negatively charged Au 25− nanoclusters. The studies …
Opportunities and Challenges in CO2 Reduction by Gold- and Silver-Based Electrocatalysts: From Bulk Metals to Nanoparticles and Atomically Precise Nanoclusters
To tackle the excessive emission of greenhouse gas CO2, electrocatalytic reduction has
been recognized as a promising way. Given the multielectron, multiproduct nature of the …
been recognized as a promising way. Given the multielectron, multiproduct nature of the …
N-Heterocyclic Carbene-Stabilized Hydrido Au24 Nanoclusters: Synthesis, Structure, and Electrocatalytic Reduction of CO2
VK Kulkarni, BN Khiarak, S Takano… - Journal of the …, 2022 - ACS Publications
Atomically precise hydrido gold nanoclusters are extremely rare but interesting due to their
potential applications in catalysis. By optimization of molecular precursors, we have …
potential applications in catalysis. By optimization of molecular precursors, we have …
Atomically Precise Gold Nanoclusters as Model Catalysts for Identifying Active Sites for Electroreduction of CO2
Accurate identification of active sites is critical for elucidating catalytic reaction mechanisms
and developing highly efficient and selective electrocatalysts. Herein, we report the atomic …
and developing highly efficient and selective electrocatalysts. Herein, we report the atomic …
Transplanting Gold Active Sites into Non-Precious-Metal Nanoclusters for Efficient CO2-to-CO Electroreduction
Electrocatalytic CO2 reduction reaction (CO2RR) is greatly facilitated by Au surfaces.
However, large fractions of underlying Au atoms are generally unused during the catalytic …
However, large fractions of underlying Au atoms are generally unused during the catalytic …
Elucidating the active sites for CO 2 electroreduction on ligand-protected Au 25 nanoclusters
Using density functional theory (DFT) calculations, we investigated the electrochemical
reduction of CO2 and the competing H2 evolution reaction on ligand-protected Au25 …
reduction of CO2 and the competing H2 evolution reaction on ligand-protected Au25 …
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO2 to CO
We report selective electrocatalytic reduction of carbon dioxide to carbon monoxide on gold
nanoparticles (NPs) in 0.5 M KHCO3 at 25° C. Among monodisperse 4, 6, 8, and 10 nm NPs …
nanoparticles (NPs) in 0.5 M KHCO3 at 25° C. Among monodisperse 4, 6, 8, and 10 nm NPs …
Influence of Atomic-Level Morphology on Catalysis: The Case of Sphere and Rod-Like Gold Nanoclusters for CO2 Electroreduction
Gold-based materials hold promise in electrocatalytic reduction of CO2 to fuels. However,
the polydispersity of conventional gold nanostructures limits mechanistic studies. Here, we …
the polydispersity of conventional gold nanostructures limits mechanistic studies. Here, we …
Ligand‐Protected Au55 with a Novel Structure and Remarkable CO2 Electroreduction Performance
XK Wan, JQ Wang, QM Wang - … Chemie International Edition, 2021 - Wiley Online Library
A Au55 nanocluster with the composition of [Au55 (p‐MBT) 24 (Ph3P) 6](SbF6) 3 (p‐MBT= 4‐
methylbenzenethiolate) is synthesized via direct reduction of gold‐phosphine and gold …
methylbenzenethiolate) is synthesized via direct reduction of gold‐phosphine and gold …