Dislocation-mediated conductivity in oxides: Progress, challenges, and opportunities

MD Armstrong, KW Lan, Y Guo, NH Perry - ACS nano, 2021 - ACS Publications
Dislocations in ionic solids are topological extended defects that modulate composition,
strain, and charge over multiple length scales. As such, they provide an extra degree of …

Donor and acceptor-like self-doping by mechanically induced dislocations in bulk TiO2

QK Muhammad, L Porz, A Nakamura, K Matsunaga… - Nano Energy, 2021 - Elsevier
Dislocations have been recently introduced as a novel tool to tailor the conductivity of
functional ceramics. However, tuning strategies suffer from poor insight into the structural …

Conductivity control via minimally invasive anti-Frenkel defects in a functional oxide

DM Evans, TS Holstad, AB Mosberg, DR Småbråten… - Nature materials, 2020 - nature.com
Utilizing quantum effects in complex oxides, such as magnetism, multiferroicity and
superconductivity, requires atomic-level control of the material's structure and composition …

Atomic scale origin of enhanced ionic conductivity at crystal defects

B Feng, R Ishikawa, A Kumamoto, N Shibata… - Nano …, 2019 - ACS Publications
In oxide materials, the presence of dislocations often strongly affects the properties of thin
film and multilayer devices. Although it was reported that ionic conduction can be enhanced …

Dislocation-mediated electronic conductivity in rutile

QK Muhammad, H Bishara, L Porz, C Dietz… - Materials Today …, 2022 - Elsevier
It has been recently shown that doping-like properties can be introduced into functional
ceramics by inducing dislocations. Especially for TiO 2, donor and acceptor-like behavior …

Conceptual framework for dislocation-modified conductivity in oxide ceramics deconvoluting mesoscopic structure, core, and space charge exemplified for SrTiO3

L Porz, T Frömling, A Nakamura, N Li, R Maruyama… - ACS …, 2020 - ACS Publications
The introduction of dislocations is a recently proposed strategy to tailor the functional and
especially the electrical properties of ceramics. While several works confirm a clear impact of …

Dislocations in SrTiO3: Easy To Reduce but Not so Fast for Oxygen Transport

D Marrocchelli, L Sun, B Yildiz - Journal of the American Chemical …, 2015 - ACS Publications
The effect of dislocations on the chemical, electrical and transport properties in oxide
materials is important for electrochemical devices, such as fuel cells and resistive switches …

A dislocation core in titanium dioxide and its electronic structure

R Sun, Z Wang, N Shibata, Y Ikuhara - Rsc Advances, 2015 - pubs.rsc.org
Insulating titanium dioxide finds numerous technological applications where dislocations
can have profound implications for its performances. Herein, by combining advanced …

The role of cation ordering and disordering on mass transport in complex oxides

CR Kreller, BP Uberuaga - Current Opinion in Solid State and Materials …, 2021 - Elsevier
Mass transport is one of the most fundamental properties of a material and dictates its
potential use for a range of applications. In simple materials, mass transport is determined …

Dislocation-mediated oxygen–ionic conductivity in yttria-stabilized zirconia

QK Muhammad, M Scherer, AK Opitz, S Taibl… - ACS Nano, 2022 - ACS Publications
Yttria-stabilized zirconia (YSZ) has become an indispensable solid electrolyte material in
modern solid oxide fuel and electrolysis cells (SOFCs/SOECs) as well as oxygen sensors …