Industrial synthesis of reactive silicones: Reaction mechanisms and processes

T Köhler, A Gutacker, E Mejía - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Silicones and silicone rubbers are ubiquitous in our daily lives, being used in a broad range
of applications ranging from consumer products and adhesives to medicinal and electronic …

Catalytic systems for the cross‐linking of organosilicon polymers

D Wang, J Klein, E Mejía - Chemistry–An Asian Journal, 2017 - Wiley Online Library
Silicones and silicone rubbers are omnipresent in household and industrial products such
as lubricants, coatings, sealants, insulators, medical devices, etc. This plethora of …

Autoxidation: catalyst-free route to silicone rubbers by crosslinking Si–H functional groups

MY Wong, AF Schneider, G Lu, Y Chen, MA Brook - Green Chemistry, 2019 - pubs.rsc.org
Most traditional methods for silicone elastomer preparation involve catalysts whose
incomplete removal can result in compromised thermal stability of the product elastomers …

New control over silicone synthesis using SiH chemistry: The Piers–Rubinsztajn reaction

MA Brook - Chemistry–A European Journal, 2018 - Wiley Online Library
There is a strong imperative to synthesize polymers with highly controlled structures and
narrow property ranges. Silicone polymers do not lend themselves to this paradigm because …

The use of the Thiol-Ene addition click reaction in the chemistry of organosilicon compounds: an alternative or a supplement to the classical hydrosilylation?

I Krizhanovskiy, M Temnikov, Y Kononevich… - Polymers, 2022 - mdpi.com
This review presents the main achievements in the use of the thiol-ene reaction in the
chemistry of silicones. Works are considered, starting from monomers and ending with …

Direct synthesis of methylchlorosilanes: catalysts, mechanisms, reaction conditions, and reactor designs

P Zhang, D Zhang, J Dong, G Chen… - … Process Research & …, 2022 - ACS Publications
Silicone polymers are produced commercially mainly from methylchlorosilanes prepared by
direct synthesis. The yield and selectivity of this synthetic process depend not only on …

Functional silicone oils and elastomers: new routes lead to new properties

MA Brook - Chemical Communications, 2023 - pubs.rsc.org
Silicones are mostly utilized for their stability to a range of vigorous environmental
conditions, which arises, in part, from the lack of functionality in finished products. The …

Testing the functional tolerance of the Piers–Rubinsztajn reaction: A new strategy for functional silicones

JB Grande, DB Thompson, F Gonzaga… - Chemical …, 2010 - pubs.rsc.org
Testing the functional tolerance of the Piers–Rubinsztajn reaction: a new strategy for
functional silicones - Chemical Communications (RSC Publishing) DOI:10.1039/C0CC00369G …

[PDF][PDF] Silicones in industrial applications

M Andriot, SH Chao, A Colas, S Cray, F de Buyl… - Inorganic …, 2007 - researchgate.net
Silicones in industry usually refer to linear polydimethylsiloxanes. A combination of
properties such as their backbone flexibility, low intermolecular interactions, low surface …

Sequential functionalization of a natural crosslinker leads to designer silicone networks

SE Laengert, AF Schneider, E Lovinger… - Chemistry–An Asian …, 2017 - Wiley Online Library
Precise silicone networks are difficult to prepare from multiple starting materials because of
poor spatial control over crosslink location, competing side reactions, and incompatible …