Stoichiometric reaction of tetrasilanol octaphenyl double-decker shaped silsesquioxanes
(DDSQ-(Ph) 8 (OH) 4) with difunctional dichlorosilanes (R 1 R 2 SiCl2) provided a new class …

Double-decker silsesquioxanes have gained a high reputation in many branches of
chemistry and process development. In particular, catalytic processes that convert double …

In this work, we report the preparation, isolation, and characterization of a family of double-
decker silsesquioxane architectures starting from the previously reported DDSQ-Me2H2 …

Herein, we disclose an unexpected Si–O–Si cage reorganization that was observed during
the standard hydrolytic condensation procedure of tetrasilanol double-decker …

Silica and substances, in which the structure of the unit SiO2 is significant, or the silicones
field, where the R2SiO unit predominates, have historically dominated the investigation of …

Bisfunctional dichlorosilanes were reacted with tetrasilanol of double-decker shaped
octaphenylsilsesquioxane (DDSQ) to form fully condensed DDSQ compounds. The …

Polyhedral oligomeric silsesquioxanes (POSS) with a rigid inorganic Si-O-Si core and
flexible and reactive and/or inert organic coronae have attracted much attention. Their …

By virtue of regio-and geometric isomers, functionalized double-decker silsesquioxanes
(DDSQ) may offer unique access to silsesquioxane-based hybrid materials with multifaceted …

Herein, we report an efficient synthesis and functionalization of trifunctional open-cage-type
silsesquioxanes. The method proposed has been successfully applied for the synthesis of a …

Polyhedral Silsesquioxanes are a wide class of organic-inorganic, ie hybrid compounds,
containing well defined nanosized, 3D inorganic core of Si-O-Si bonds and organic …