Platonic and Archimedean solids in discrete metal-containing clusters

XM Luo, YK Li, XY Dong, SQ Zang - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …

Recent advances in the structural design and regulation of lanthanide clusters: Formation and self-assembly mechanisms

YL Li, HL Wang, ZH Zhu, FP Liang, HH Zou - Coordination Chemistry …, 2023 - Elsevier
The design and synthesis of lanthanide clusters with novel topological connections and
desirable properties are attracting extensive attention. Researchers have obtained …

Structural chemistry of giant metal based supramolecules

AV Virovets, E Peresypkina, M Scheer - Chemical Reviews, 2021 - ACS Publications
The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …

Mesoporous assembly of aluminum molecular rings for iodine capture

S Yao, WH Fang, Y Sun, ST Wang… - Journal of the American …, 2021 - ACS Publications
The effective capture and storage of radioiodine are of worldwide interest for sustainable
nuclear energy. However, the direct observation of ambiguous binding sites that …

[HTML][HTML] Lanthanide molecular cluster-aggregates as the next generation of optical materials

DA Gálico, CMS Calado, M Murugesu - Chemical Science, 2023 - pubs.rsc.org
In this perspective, we provide an overview of the recent achievements in luminescent
lanthanide-based molecular cluster-aggregates (MCAs) and illustrate why MCAs can be …

In-situ synthesis of molecular magnetorefrigerant materials

SJ Liu, SD Han, JP Zhao, J Xu, XH Bu - Coordination Chemistry Reviews, 2019 - Elsevier
Zero-dimensional cluster complexes and coordination polymers for magnetic refrigeration
have attracted great interest in the last decade. In-situ synthesis is a widely-used method to …

Gd(OH)F2: A Promising Cryogenic Magnetic Refrigerant

Q Xu, B Liu, M Ye, G Zhuang, L Long… - Journal of the American …, 2022 - ACS Publications
Magnetic refrigerants with a large magnetocaloric effect (MCE) in a wide temperature range
and low magnetic ordering temperature (T o) in the sub-kelvin temperature region are not …

The Gigantic {Ni36Gd102} Hexagon: A Sulfate-Templated “Star-of-David” for Photocatalytic CO2 Reduction and Magnetic Cooling

WP Chen, PQ Liao, PB Jin, L Zhang… - Journal of the …, 2020 - ACS Publications
Gigantic coordination molecules assembled from a large number of metal ions and organic
ligands are structurally and functionally challenging to characterize. Here we show that a …

Polyoxometalate‐Structured Materials: Molecular Fundamentals and Electrocatalytic Roles in Energy Conversion

T Ma, R Yan, X Wu, M Wang, B Yin, S Li… - Advanced …, 2024 - Wiley Online Library
Polyoxometalates (POMs), a kind of molecular metal oxide cluster with unique physical–
chemical properties, have made essential contributions to creating efficient and robust …

Exploring the Performance Improvement of Magnetocaloric Effect Based Gd-Exclusive Cluster Gd60

XM Luo, ZB Hu, Q Lin, W Cheng, JP Cao… - Journal of the …, 2018 - ACS Publications
Despite wide potential applications of Gd-clusters in magnetocaloric effect (MCE) owing to f7
electron configuration of Gd (III), the structural improvement in order to enhance MCE …