Singlet oxygen evolution from layered transition metal oxide cathode materials and its implications for lithium-ion batteries

J Wandt, ATS Freiberg, A Ogrodnik, HA Gasteiger - Materials Today, 2018 - Elsevier
For achieving higher energy density lithium-ion batteries, the improvement of cathode active
materials is crucial. The most promising cathode materials are nickel-rich layered oxides …

Exploring Oxygen Activity in the High Energy P2-Type Na0.78Ni0.23Mn0.69O2 Cathode Material for Na-Ion Batteries

C Ma, J Alvarado, J Xu, RJ Clément… - Journal of the …, 2017 - ACS Publications
Large-scale electric energy storage is fundamental to the use of renewable energy.
Recently, research and development efforts on room-temperature sodium-ion batteries …

Zinc-doped high-nickel, low-cobalt layered oxide cathodes for high-energy-density lithium-ion batteries

Z Cui, Q Xie, A Manthiram - ACS Applied Materials & Interfaces, 2021 - ACS Publications
High-Ni layered oxides with Ni contents greater than 90% are promising cathode candidates
for high-energy-density Li-ion batteries. However, drastic electrode–electrolyte reactions …

High-Voltage Cycling Induced Thermal Vulnerability in LiCoO2 Cathode: Cation Loss and Oxygen Release Driven by Oxygen Vacancy Migration

C Sun, X Liao, F Xia, Y Zhao, L Zhang, S Mu, S Shi… - ACS …, 2020 - ACS Publications
The release of the lattice oxygen due to the thermal degradation of layered lithium transition
metal oxides is one of the major safety concerns in Li-ion batteries. The oxygen release is …

Elucidating anionic oxygen activity in lithium-rich layered oxides

J Xu, M Sun, R Qiao, SE Renfrew, L Ma, T Wu… - Nature …, 2018 - nature.com
Recent research has explored combining conventional transition-metal redox with anionic
lattice oxygen redox as a new and exciting direction to search for high-capacity lithium-ion …

Reaction mechanisms of layered lithium‐rich cathode materials for high‐energy lithium‐ion batteries

S Zhao, K Yan, J Zhang, B Sun… - Angewandte Chemie …, 2021 - Wiley Online Library
Layered lithium‐rich cathode materials have attracted extensive interest owing to their high
theoretical specific capacity (320–350 mA hg− 1). However, poor cycling stability and …

Structural insights into the formation and voltage degradation of lithium-and manganese-rich layered oxides

W Hua, S Wang, M Knapp, SJ Leake… - Nature …, 2019 - nature.com
One major challenge in the field of lithium-ion batteries is to understand the degradation
mechanism of high-energy lithium-and manganese-rich layered cathode materials. Although …

TiC3 Monolayer with High Specific Capacity for Sodium-Ion Batteries

T Yu, Z Zhao, L Liu, S Zhang, H Xu… - Journal of the American …, 2018 - ACS Publications
Sodium-ion batteries (SIBs) have attracted considerable attention due to the intrinsic safety
and high abundance of sodium. However, the lack of high-performance anode materials …

Scavenging Materials to Stabilize LiPF6‐Containing Carbonate‐Based Electrolytes for Li‐Ion Batteries

JG Han, K Kim, Y Lee, NS Choi - Advanced Materials, 2019 - Wiley Online Library
In conjunction with electrolyte additives used for tuning the interfacial structures of
electrodes, functional materials that eliminate or deactivate reactive substances generated …

Manganese oxidation as the origin of the anomalous capacity of Mn-containing Li-excess cathode materials

MD Radin, J Vinckeviciute, R Seshadri, A Van der Ven - Nature Energy, 2019 - nature.com
The lithium-excess manganese oxides are a candidate cathode material for the next
generation of Li-ion batteries because of their ability to reversibly intercalate more Li than …