The thermodynamic stability of radicals as defined through isodesmic hydrogen transfer
reactions has been explored at a variety of theoretical levels. Radical stabilization energies …

A unified approach toward the taiwaniaquinoids that has yielded four natural products is
described. A new variant of the Nazarov reaction with concomitant formation of an enol …

(+)-Catechin and (−)-epicatechin are two flavonoid stereoisomers very abundant in
vegetable tissues which present high antioxidant activity in living systems. It is known that …

The demand for novel effective antioxidant-based drugs has led to the synthesis and
evaluation of the antioxidant potential in several molecules derived from natural compounds …

A practical and an efficient synthesis of three building blocks of tetrahydroisoquinoline
alkaloid Ecteinascidin-743 was accomplished, starting from readily available piperonal, 2 …

Effects of α-tocopherol, PMC, and a number of the respective sulfur-containing analogues on
reactions involving various organic radicals were studied. The test compounds were found …

An (RO) B3LYP/LANL2DZdp//B3LYP/LANL2DZ model for the prediction of the homolytic
bond dissociation enthalpy (BDE) and adiabatic ionisation potential (IP) of phenolic …

The antioxidant activities of several hydroxy‐substituted 4‐thiaflavanes, compounds 1–3,
were determined by measuring their ability of inhibiting the autoxidation of styrene or …

The main objective of the thesis was to develop novel synthetic compounds with antioxidant
activity superior to Vitamin E aimed at reducing free radical-induced cell damage. The bond …

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