Thirty Years of (TMS)3SiH: A Milestone in Radical-Based Synthetic Chemistry

C Chatgilialoglu, C Ferreri, Y Landais… - Chemical …, 2018 - ACS Publications
This review is an update on tris (trimethylsilyl) silane, TTMSS, in organic chemistry, focusing
on the advancements of the past decade. The overview includes a wide range of chemical …

Photoinduced remote functionalisations by iminyl radical promoted C− C and C− H bond cleavage cascades

EM Dauncey, SP Morcillo, JJ Douglas… - Angewandte …, 2018 - Wiley Online Library
A photoinduced cascade strategy leading to a variety of differentially functionalised nitriles
and ketones has been developed. These reactions rely on the oxidative generation of iminyl …

Photochemical reactions as key steps in five-membered N-heterocycle synthesis

N Kaur - Synthetic Communications, 2018 - Taylor & Francis
The chemists have been interested in light as an energy source to induce chemical
reactions since the beginning of scientific chemistry. This review summarizes the chemistry …

Direct Photocatalytic Synthesis of Medium‐Sized Lactams by C− C Bond Cleavage

N Wang, QS Gu, ZL Li, Z Li, YL Guo… - Angewandte Chemie …, 2018 - Wiley Online Library
Reported is a novel two‐step ring‐expansion strategy for expeditious synthesis of all ring
sizes of synthetically challenging (hetero) aryl‐fused medium‐sized lactams from readily …

Photochemical mediated reactions in five-membered O-heterocycles synthesis

N Kaur - Synthetic Communications, 2018 - Taylor & Francis
Photochemical mediated synthesis in organic chemistry is a highly expanding area. This is a
widely exploited area of research for the construction of new pharmaceutically significant …

Enantioselective total syntheses of (+)-hippolachnin A,(+)-gracilioether A,(−)-gracilioether E, and (−)-gracilioether F

Q Li, K Zhao, A Peuronen, K Rissanen… - Journal of the …, 2018 - ACS Publications
The Plakortin polyketides represent a structurally and biologically fascinating class of marine
natural products. Herein, we report a unified strategy that enables the divergent syntheses of …

Photochemical irradiation: Seven and higher membered O-heterocycles

N Kaur - Synthetic Communications, 2018 - Taylor & Francis
The seven-membered heterocycles are widely present in biologically active compounds
which provided a reason for the development of protocols for their synthesis. Photochemical …

9‐Membered Carbocycles: Strategies and Tactics for their Synthesis

T Huber, RE Wildermuth… - Chemistry–A European …, 2018 - Wiley Online Library
Many natural products comprising a nine‐membered carbocyclic core structure exhibit
interesting biological effects. However, only a minority have succumbed to their synthesis in …

Synthesis of seven and higher membered nitrogen containing heterocycles using photochemical irradiation

N Kaur - Synthetic Communications, 2018 - Taylor & Francis
Photochemical reactions have been applied for the synthesis of complex targets in many
examples recently. In many cases, these processes provide access to unique modes of …

Photochemical reactions for the synthesis of six-membered O-heterocycles

N Kaur - Current Organic Synthesis, 2018 - ingentaconnect.com
Background: The chemists have been interested in light as an energy source to induce
chemical reactions since the beginning of the scientific chemistry. This review summarizes …