Heterocyclic compounds bearing triazole and quinoxaline possess significant
pharmacological activities. Herein, a new quinoxaline derivative containing 1, 2, 3-triazole …

A novel, efficient, convenient and environmentally friendly approach for the synthesis of
nitriles and imines from primary amines has been developed. Using commercially available …

The oxidation of primary azides to aldehydes constitutes a convenient but underdeveloped
transformation for which no efficient methods are available. Here, we demonstrate that …

The traditional Staudinger/aza-Wittig reaction represents one of the most powerful tools for
imine formation. However, for this multistep procedure, the sacrificial phosphine has to be …

The photodecomposition of azides to generate nitrenes usually requires wavelengths in
the< 300 nm region. In this study, we show that this reaction can be readily performed in the …

Enzymatic dioxygenation of benzyl azide by toluene dioxygenase (TDO) produces
significant amounts of the cis‐cyclohexadienediol derived from benzonitrile, along with the …

Quantum chemical calculations using Density Functional Theory (DFT) at the B3LYP/6-31++
G (d, p) basis set level were performed to investigate the azide group rotation from the trans …

A cascade reaction of homopropargyl azides in the presence of a Cu catalyst was achieved,
affording 3-(trifluoromethyl) but-3-enenitriles with good yields and excellent regioselectivity …

Nickel boride catalyst prepared in situ from NiCl 2 and sodium borohydride allowed, in the
presence of an aqueous solution of TEMPO-oxidized nanocellulose (0.01 wt%), the …

Catalytic chemoselective hydrogenation of organic azides using palladium nanoparticles
stabilized by alkyne derivatives was studied. A broad range of aromatic and aliphatic azides …