This review highlights the use of the oxidative boron Heck reaction in enantioselective Heck-
type couplings. The enantioselective oxidative boron Heck reaction overcomes several …

Due to the versatile reactivity and molecular complexity, as well as diversity, electron‐rich
alkenes bearing nitrogen, oxygen, or sulfur atoms have been regarded as versatile reagents …

Rh(III)-Catalyzed Oxidative Coupling of Benzoic Acids with Geminal-Substituted Vinyl
Acetates: Synthesis of 3-Substituted Isocoumarins | The Journal of Organic Chemistry ACS …

The development of organometallic single-site catalysts (SSCs) has inspired the designs of
new heterogeneous catalysts with high efficiency. Nevertheless, the application of SSCs in …

Abstract Thiosemicarbazones of 2-formylpyridine, 2-aceylpyridine and 2-benzoylpyridine,
abbreviated in general as HL-R (where H depicts the acidic hydrogen and R the fragment …

An efficient Rh (III)-catalyzed direct ortho-C–H olefination of acetanilides with vinyl acetate
was developed. This protocol provides a straightforward pathway to a series of (E)-2 …

Oxidative Heck couplings have been successfully developed for 2, 2-disubstituted
cyclopentene-1, 3-diones. The direct coupling onto the 2, 2-disubstituted cyclopentene-1, 3 …

Abstract The ruthenium‐catalyzed Fujiwara–Moritani reaction (oxidative‐Heck reaction) of
Weinreb amides is reported herein. The reaction affords exclusively ortho‐C− H olefination …

This review summarizes the applications of vinyl sulfonate and vinyl acetate as green
alternatives for vinyl bromide in cross-coupling reactions. In the first part, the preparation of …

Abstract A palladium‐catalyzed 1, 2‐diarylation of vinyl esters with arylboronic acids in water
has been developed. This newly elaborated protocol features a good functional group …