Oxide cathodes: functions, instabilities, self healing, and degradation mitigations

Y Dong, J Li - Chemical Reviews, 2022 - ACS Publications
Recent progress in high-energy-density oxide cathodes for lithium-ion batteries has pushed
the limits of lithium usage and accessible redox couples. It often invokes hybrid anion-and …

[HTML][HTML] Application of electrochemical impedance spectroscopy to commercial Li-ion cells: A review

N Meddings, M Heinrich, F Overney, JS Lee… - Journal of Power …, 2020 - Elsevier
Electrochemical impedance spectroscopy (EIS) is a widely applied non-destructive method
of characterisation of Li-ion batteries. Despite its ease of application, there are inherent …

Ultra-high-voltage Ni-rich layered cathodes in practical Li metal batteries enabled by a sulfonamide-based electrolyte

W Xue, M Huang, Y Li, YG Zhu, R Gao, X Xiao… - Nature Energy, 2021 - nature.com
By increasing the charging voltage, a cell specific energy of> 400 W h kg− 1 is achievable
with LiNi0. 8Mn0. 1Co0. 1O2 in Li metal batteries. However, stable cycling of high-nickel …

Polycrystalline and single crystalline NCM cathode materials—quantifying particle cracking, active surface area, and lithium diffusion

E Trevisanello, R Ruess, G Conforto… - Advanced Energy …, 2021 - Wiley Online Library
Representatives of the LixNi1− y− zCoyMnzO2 (NCM) family of cathode active materials
(CAMs) with high nickel content are becoming the CAM of choice for high performance …

Reductive gas manipulation at early self-heating stage enables controllable battery thermal failure

Y Wang, X Feng, Y Peng, F Zhang, D Ren, X Liu, L Lu… - Joule, 2022 - cell.com
Li-ion batteries are regarded as unsafe due to the volatility and flammability of the organic
liquid electrolytes. However, research on substitutes (solid, inorganic, etc.) still encounters …

Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries

C Xu, K Märker, J Lee, A Mahadevegowda… - Nature Materials, 2021 - nature.com
Ni-rich layered cathode materials are among the most promising candidates for high-energy-
density Li-ion batteries, yet their degradation mechanisms are still poorly understood. We …

Phase behavior during electrochemical cycling of Ni‐rich cathode materials for Li‐ion batteries

C Xu, PJ Reeves, Q Jacquet… - Advanced Energy …, 2021 - Wiley Online Library
Although layered lithium nickel‐rich oxides have become the state‐of‐the‐art cathode
materials for lithium‐ion batteries in electric vehicle (EV) applications, they can suffer from …

Rapid determination of solid-state diffusion coefficients in Li-based batteries via intermittent current interruption method

YC Chien, H Liu, AS Menon, WR Brant… - Nature …, 2023 - nature.com
The galvanostatic intermittent titration technique (GITT) is considered the go-to method for
determining the Li+ diffusion coefficients in insertion electrode materials. However, GITT …

Long-term cyclability of NCM-811 at high voltages in lithium-ion batteries: an in-depth diagnostic study

W Li, X Liu, Q Xie, Y You, M Chi… - Chemistry of …, 2020 - ACS Publications
High-nickel layered oxides, such as LiNi0. 8Co0. 1Mn0. 1O2 (NCM-811), offer higher energy
density than their low-nickel counterparts at a given voltage and are gaining major traction in …

In‐depth analysis of the degradation mechanisms of high‐nickel, low/no‐cobalt layered oxide cathodes for lithium‐ion batteries

S Lee, W Li, A Dolocan, H Celio, H Park… - Advanced Energy …, 2021 - Wiley Online Library
A rational compositional design of high‐nickel, cobalt‐free layered oxide materials for high‐
energy and low‐cost lithium‐ion batteries would be expected to further propel the …