Methyl complexes of the transition metals
J Campos, J López‐Serrano, R Peloso… - … –A European Journal, 2016 - Wiley Online Library
Organometallic chemistry can be considered as a wide area of knowledge that combines
concepts of classic organic chemistry, that is, based essentially on carbon, with molecular …
concepts of classic organic chemistry, that is, based essentially on carbon, with molecular …
Synthesis of Heterobimetallic Ru Mn Complexes and the Coupling Reactions of Epoxides with Carbon Dioxide Catalyzed by these Complexes
ML Man, KC Lam, WN Sit, SM Ng… - … A European Journal, 2006 - Wiley Online Library
Abstract The heterobimetallic complexes [(η5‐C5H5) Ru (CO)(μ‐dppm) Mn (CO) 4] and [(η5‐
C5Me5) Ru (μ‐dppm)(μ‐CO) 2Mn (CO) 3](dppm= bis‐diphenylphosphinomethane) have …
C5Me5) Ru (μ‐dppm)(μ‐CO) 2Mn (CO) 3](dppm= bis‐diphenylphosphinomethane) have …
Alkyl, silyl, and phosphane ligands—classical ligands in nonclassical bonding modes
P Braunstein, NM Boag - Angewandte Chemie International …, 2001 - Wiley Online Library
Alkyl, silyl, and phosphane ligands are amongst the most familiar and ubiquitous ligands in
organometallic and coordination chemistry. The C, Si, and P donor atoms of these ligands …
organometallic and coordination chemistry. The C, Si, and P donor atoms of these ligands …
DFT Mechanistic Insights into the Alkyne Insertion Reaction Affording Diiron μ-Vinyliminium Complexes and New Functionalization Pathways
G Ciancaleoni, S Zacchini, V Zanotti… - Organometallics, 2018 - ACS Publications
Insertion of propyne or 2-butyne into the Fe–carbyne bond belonging to the fragment
[Fe2Cp2 (CO)(μ-CO){μ-CNMe (R)}]+(R= Me or Xyl= 2, 6-C6H3Me2) was investigated via …
[Fe2Cp2 (CO)(μ-CO){μ-CNMe (R)}]+(R= Me or Xyl= 2, 6-C6H3Me2) was investigated via …
Unsymmetric Ir2 and RhIr Dinuclear Complexes Supported by a Linear Tetraphosphine meso-dpmppp, Showing High Reactivity for O2, H2, and HCl
T Nakajima, M Kotani, Y Maeda, M Sato, K Iwai… - Inorganic …, 2024 - ACS Publications
Unsymmetric dinuclear Ir (I) complexes,[Ir2Cl2 (L)(meso-dpmppp)](L= XylNC (1aIr 2), t
BuNC (1bIr 2), CO (1cIr 2)), were synthesized using meso-Ph2PCH2P (Ph)(CH2) 3P (Ph) …
BuNC (1bIr 2), CO (1cIr 2)), were synthesized using meso-Ph2PCH2P (Ph)(CH2) 3P (Ph) …
Chemistry of Metal− Metal-Bonded Early− Late Heterobimetallics: Cooperative Reactions of Functional Groups at a Persistent Organometallic Zr− Rh Framework
C Cornelissen, G Erker, G Kehr, R Fröhlich - Organometallics, 2005 - ACS Publications
The reaction of (C5H4− PPh2) 2Zr (CH3) 2 (5a) with HRh (CO)(PPh3) 3 (6) leads to
methane evolution and the formation of the early− late heterobimetallic complex [(μ-C5H4 …
methane evolution and the formation of the early− late heterobimetallic complex [(μ-C5H4 …
Synthesis, characterization and reactivity of heterobimetallic complexes (η 5-C 5 R 5) Ru (CO)(μ-dppm) M (CO) 2 (η 5-C 5 H 5)(R= H, CH 3; M= Mo, W) …
ML Man, Z Zhou, SM Ng, CP Lau - Dalton Transactions, 2003 - pubs.rsc.org
The heterobimetallic complexes [(η5-C5R5) Ru (CO)(μ-dppm) M (CO) 2 (η5-C5H5)](M= Mo,
W; R= H, CH3)(1–4) are prepared by metathetical reactions between (η5-C5R5) Ru (dppm) …
W; R= H, CH3)(1–4) are prepared by metathetical reactions between (η5-C5R5) Ru (dppm) …
A theoretical study of metal–metal cooperativity in the homogeneous water gas shift reaction
N Kuriakose, S Kadam, K Vanka - Inorganic chemistry, 2012 - ACS Publications
The possibility of metal–metal cooperativity in improving the yield of the homogeneous water
gas shift reaction (WGSR) has been investigated through full quantum mechanical density …
gas shift reaction (WGSR) has been investigated through full quantum mechanical density …
Niobium/rhodium bimetallic complexes: synthesis, structure, and catalytic hydrosilylation of acetophenone and benzaldehyde
S Leelasubcharoen, PA Zhizhko, LG Kuzmina… - …, 2009 - ACS Publications
Reactions of a new imido phosphido complex, Cp2Nb ( NBut)(PPh2)(1), with olefin
complexes of rhodium afford two types of compounds. With [(μ-Cl) Rh (C2H4) 2] 2, an …
complexes of rhodium afford two types of compounds. With [(μ-Cl) Rh (C2H4) 2] 2, an …
The Bridged Binding Mode as a New, Versatile Template for the Selective Activation of Carbon− Fluorine Bonds in Fluoroolefins: Activation of Trifluoroethylene
ME Slaney, DJ Anderson, MJ Ferguson… - Journal of the …, 2010 - ACS Publications
We report the selective activation of carbon− fluorine bonds in trifluoroethylene using the
diiridium complex [Ir2 (CH3)(CO) 2 (dppm) 2][OTf](1). Coordination of trifluoroethylene in a …
diiridium complex [Ir2 (CH3)(CO) 2 (dppm) 2][OTf](1). Coordination of trifluoroethylene in a …