Organic electron donors as powerful single‐electron reducing agents in organic synthesis

J Broggi, T Terme, P Vanelle - … Chemie International Edition, 2014 - Wiley Online Library
One‐electron reduction is commonly used in organic chemistry for the formation of radicals
by the stepwise transfer of one or two electrons from a donor to an organic substrate …

A review on solvent-free methods in organic synthesis

S Zangade, P Patil - Current Organic Chemistry, 2019 - ingentaconnect.com
Most of the synthetic chemical transformation reactions involve the use of different organic
solvents. Unfortunately, some of these toxic solvents are used in chemical laboratory …

A new reagent for direct difluoromethylation

Y Fujiwara, JA Dixon, RA Rodriguez… - Journal of the …, 2012 - ACS Publications
Molecular scaffolds containing alkylfluorine substituents are desired in many areas of
chemical research from materials to pharmaceuticals. Herein, we report the invention of a …

Palladium-catalyzed difluoroalkylation of Isocyanides: access to difluoroalkylated phenanthridine derivatives

JW Gu, X Zhang - Organic letters, 2015 - ACS Publications
An efficient and general method for the synthesis of difluoroalkylated phenanthridine
derivatives through palladium-catalyzed reaction of difluoroalkyl bromides with isocyanides …

Synthesis, antifungal activities and molecular docking studies of benzoxazole and benzothiazole derivatives

B Luo, D Li, AL Zhang, JM Gao - Molecules, 2018 - mdpi.com
Based on benzoxazole and benzothiazole scaffold as an important pharmacophore, two
series of 2-(aryloxymethyl) benzoxazole and benzothiazole derivatives were synthesized …

[PDF][PDF] Generation of aryl anions by double electron transfer to aryl iodides from a neutral ground-state organic super electron donor (SED)

JA Murphy, S Zhou, DW Thomson… - Agewandte Chemie …, 2007 - researchgate.net
All reactions were performed in flame-dried apparatus under a nitrogen or argon
atmosphere using dry and deoxygenated solvents. A glove box (System One Glove Box …

Silver-catalyzed C–H aryloxydifluoromethylation and arylthiodifluoromethylation of heteroarenes

XL Zhu, Y Huang, XH Xu, FL Qing - Organic Letters, 2020 - ACS Publications
The oxidative C–H aryloxydifluoromethylation and arylthiodifluoromethylation of
heteroaromatic compounds through the decarboxylation of easily accessible …

Nucleophilic trifluoromethylation using trifluoromethyl iodide. A new and simple alternative for the trifluoromethylation of aldehydes and ketones

S Aït-Mohand, N Takechi, M Médebielle… - Organic …, 2001 - ACS Publications
Nucleophilic Trifluoromethylation Using Trifluoromethyl Iodide. A New and Simple Alternative
for the Trifluoromethylation of Aldehydes and Ketones | Organic Letters ACS ACS Publications …

Nucleophilic difluoromethylation and difluoromethylenation using bromodifluoromethyl phenyl sulfone

GKS Prakash, Y Wang, J Hu, GA Olah - Journal of fluorine chemistry, 2005 - Elsevier
Tetrakis (dimethylamino) ethylene (TDAE) was found to be an effective electron-transfer
agent that promoted the reactions of bromodifluoromethyl phenyl sulfone with aldehydes to …

One-pot synthesis of 2-trifluoromethyl and 2-difluoromethyl substituted benzo-1, 3-diazoles

F Ge, Z Wang, W Wan, W Lu, J Hao - Tetrahedron letters, 2007 - Elsevier
2-Trifluoromethyl and 2-difluoromethyl substituted benzimidazole, benzoxazole and
benzothiazole derivatives were efficiently prepared through a one-pot reaction of …