Frontal polymerizations: from chemical perspectives to macroscopic properties and applications

BA Suslick, J Hemmer, BR Groce, KJ Stawiasz… - Chemical …, 2023 - ACS Publications
The synthesis and processing of most thermoplastics and thermoset polymeric materials rely
on energy-inefficient and environmentally burdensome manufacturing methods. Frontal …

Photoluminescent and chromic nanomaterials for anticounterfeiting technologies: recent advances and future challenges

A Abdollahi, H Roghani-Mamaqani, B Razavi… - ACS …, 2020 - ACS Publications
Counterfeiting and inverse engineering of security and confidential documents, such as
banknotes, passports, national cards, certificates, and valuable products, has significantly …

Rapid energy-efficient manufacturing of polymers and composites via frontal polymerization

ID Robertson, M Yourdkhani, PJ Centellas, JE Aw… - Nature, 2018 - nature.com
Thermoset polymers and composite materials are integral to today's aerospace, automotive,
marine and energy industries and will be vital to the next generation of lightweight, energy …

A bi-functional device for self-powered electrochromic window and self-rechargeable transparent battery applications

J Wang, L Zhang, L Yu, Z Jiao, H Xie, XW Lou… - Nature …, 2014 - nature.com
Electrochromic smart windows are regarded as a good choice for green buildings. However,
conventional devices need external biases to operate, which causes additional energy …

[图书][B] An introduction to nonlinear chemical dynamics: oscillations, waves, patterns, and chaos

IR Epstein, JA Pojman - 1998 - books.google.com
Just a few decades ago, chemical oscillations were thought to be exotic reactions of only
theoretical interest. Now known to govern an array of physical and biological processes …

Free-radical frontal polymerization: Self-propagating thermal reaction waves

JA Pojman, VM Ilyashenko, AM Khan - Journal of the Chemical Society …, 1996 - pubs.rsc.org
Frontal polymerization is a mode of converting monomer into polymer via a localized
reaction zone that propagates. Such fronts can exist with free-radical polymerization or …

Self‐Regulative Direct Ink Writing of Frontally Polymerizing Thermoset Polymers

JE Aw, X Zhang, AZ Nelson, LM Dean… - Advanced Materials …, 2022 - Wiley Online Library
The ability to manufacture highly intricate designs is one of the key advantages of 3D
printing. Achieving high dimensional accuracy requires precise, often time‐consuming …

Graphene-containing thermoresponsive nanocomposite hydrogels of poly (N-isopropylacrylamide) prepared by frontal polymerization

V Alzari, D Nuvoli, S Scognamillo, M Piccinini… - Journal of Materials …, 2011 - pubs.rsc.org
Frontal polymerization has been successfully used to synthesize poly (N-
isopropylacrylamide) nanocomposite hydrogels containing graphene. The latter was directly …

Review on UV-induced cationic frontal polymerization of epoxy monomers

MS Malik, S Schlögl, M Wolfahrt, M Sangermano - Polymers, 2020 - mdpi.com
Ultraviolet (UV)-induced cationic frontal polymerization has emerged as a novel technique
that allows rapid curing of various epoxy monomers upon UV irradiation within a few …

Three-dimensional modeling of frontal polymerization for rapid, efficient, and uniform thermoset composites manufacturing

A Tarafdar, C Jia, W Hu, ID Hosein, KK Fu… - Composites Part B …, 2023 - Elsevier
Due to the incapability of one-dimensional (1D) and two-dimensional (2D) models in
simulating the frontal polymerization (FP) process in laminated composites with multiple …