Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase

ST Stripp, BR Duffus, V Fourmond, C Léger… - Chemical …, 2022 - ACS Publications
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

Hydrogenases

W Lubitz, H Ogata, O Rudiger, E Reijerse - Chemical reviews, 2014 - ACS Publications
The reaction takes place at a specialized metal center that dramatically increases the acidity
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …

Occurrence, classification, and biological function of hydrogenases: an overview

PM Vignais, B Billoud - Chemical reviews, 2007 - ACS Publications
If the atmosphere of the early Earth was hydrogen-rich, 1 it is reasonable to think that
hydrogenases, the enzymes enabling cells to use molecular hydrogen, were probably …

Renewable hydrogen production

J Turner, G Sverdrup, MK Mann… - … journal of energy …, 2008 - Wiley Online Library
Abstract The US Department of Energy and the National Renewable Energy Laboratory are
developing technologies to produce hydrogen from renewable, sustainable sources. A cost …

Structure/function relationships of [NiFe]-and [FeFe]-hydrogenases

JC Fontecilla-Camps, A Volbeda, C Cavazza… - Chemical …, 2007 - ACS Publications
The utilization of hydrogen by micro-organisms as a source of reducing power or of protons
as final electron acceptors is mediated by metalloenzymes called hydrogenases. The need …

Direct electrochemistry of redox enzymes as a tool for mechanistic studies

C Léger, P Bertrand - Chemical Reviews, 2008 - ACS Publications
This review regards the use of dynamic electrochemistry to study the mechanism of redox
enzymes, with exclusive emphasis on the configuration where the protein is adsorbed onto …

Accelerating molecular modeling applications with graphics processors

JE Stone, JC Phillips, PL Freddolino… - Journal of …, 2007 - Wiley Online Library
Molecular mechanics simulations offer a computational approach to study the behavior of
biomolecules at atomic detail, but such simulations are limited in size and timescale by the …

[HTML][HTML] Gates of enzymes

A Gora, J Brezovsky, J Damborsky - Chemical reviews, 2013 - ACS Publications
Enzymes are very efficient catalysts that are essential for the functioning of living organisms.
The low efficiency of biocatalysts produced de novo relative to those that have evolved …

[图书][B] Introduction to proteins: structure, function, and motion

A Kessel, N Ben-Tal - 2018 - taylorfrancis.com
Introduction to Proteins provides a comprehensive and state-of-the-art introduction to the
structure, function, and motion of proteins for students, faculty, and researchers at all levels …

[HTML][HTML] Chance and design—proton transfer in water, channels and bioenergetic proteins

CA Wraight - Biochimica et Biophysica Acta (BBA)-Bioenergetics, 2006 - Elsevier
Proton transfer and transport in water, gramicidin and some selected channels and
bioenergetic proteins are reviewed. An attempt is made to draw some conclusions about …