Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
Progress in reaction mechanisms and reactor technologies for thermochemical recycling of poly (methyl methacrylate)
EKC Moens, K De Smit, YW Marien, AD Trigilio… - Polymers, 2020 - mdpi.com
Chemical or feedstock recycling of poly (methyl methacrylate)(PMMA) by thermal
degradation is an important societal challenge to enable polymer circularity. The annual …
degradation is an important societal challenge to enable polymer circularity. The annual …
Gillespie-driven kinetic Monte Carlo algorithms to model events for bulk or solution (bio) chemical systems containing elemental and distributed species
AD Trigilio, YW Marien… - Industrial & …, 2020 - ACS Publications
Stochastic modeling techniques have emerged as a powerful tool to study the time evolution
of processes in many research fields including (bio) chemical engineering and biology. One …
of processes in many research fields including (bio) chemical engineering and biology. One …
How phase transfer increases the number of kinetic regimes from three to seven in nitroxide mediated polymerization of n-butyl acrylate in aqueous miniemulsion
One of the challenges in reversible deactivation radical polymerization (RDRP) in
miniemulsion is identifying the optimal average particle size (dp), offering both high reaction …
miniemulsion is identifying the optimal average particle size (dp), offering both high reaction …
Understanding differential microemulsion polymerization in continuous slug flow through kinetic Monte Carlo simulation
M Qiu, Y Wang, M Shang, Y Su - Chemical Engineering Journal, 2023 - Elsevier
Microreactors have been universal in polymerization and will help mitigate the residence
time distribution and viscosity if conducted in a slug flow regime. The numerical simulation of …
time distribution and viscosity if conducted in a slug flow regime. The numerical simulation of …
Coupled matrix-based Monte Carlo modeling for a mechanistic understanding of poly (methyl methacrylate) thermochemical recycling kinetics
Abstract Coupled matrix-based Monte Carlo (CMMC) modeling is applied to gain a deeper
understanding of the mechanism underlying the thermochemical degradation of poly (methyl …
understanding of the mechanism underlying the thermochemical degradation of poly (methyl …
In-depth mechanistic and kinetic investigation of sonochemically mediated atom transfer radical polymerization using modeling approach
C Bian, S Li, N Yang, H Chen, W Feng, YN Zhou… - Chemical Engineering …, 2023 - Elsevier
Mechano/sonochemically mediated reversible deactivation radical polymerization has
attracted great attention because of the novel electron transfer regulation process and high …
attracted great attention because of the novel electron transfer regulation process and high …
Roadmap for monomer conversion and chain length-dependent termination reactivity algorithms in kinetic Monte Carlo modeling of bulk radical polymerization
K De Smit, YW Marien, M Edeleva… - Industrial & …, 2020 - ACS Publications
Radical polymerization is prone to diffusional limitations on termination, leading to a rate
acceleration by the gel-effect and molecular changes, with strong increases in average …
acceleration by the gel-effect and molecular changes, with strong increases in average …
Conformational variations for surface-initiated reversible deactivation radical polymerization: From flat to curved nanoparticle surfaces
FJ Arraez, PHM Van Steenberge, J Sobieski… - …, 2021 - ACS Publications
Although progress in surface-initiated reversible deactivation radical polymerization (SI-
RDRP) has already enabled the production of increasingly novel and advanced polymer …
RDRP) has already enabled the production of increasingly novel and advanced polymer …
Comparing SG1 and TEMPO for NMP of n-butyl acrylate in miniemulsion to optimize the average particle size for rate and molecular control
Nitroxide mediated polymerization (NMP) in aqueous miniemulsion potentially offers both
control over chain length and livingness, while reducing the reaction time compared to the …
control over chain length and livingness, while reducing the reaction time compared to the …