Advances in synthetic applications of hypervalent iodine compounds

A Yoshimura, VV Zhdankin - Chemical reviews, 2016 - ACS Publications
The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Chiral hypervalent iodines: active players in asymmetric synthesis

A Parra - Chemical reviews, 2019 - ACS Publications
Asymmetric organocatalytic oxidations have been witnessed to an impressive development
in the last years thanks to the establishment of important chiral hypervalent iodines (III/V) …

Recent developments in the chemistry of polyvalent iodine compounds

VV Zhdankin, PJ Stang - Chemical reviews, 2002 - ACS Publications
The organic chemistry of polyvalent iodine compounds has experienced an unprecedented,
explosive development during the last decade of the 20th century. A quick SciFinder Scholar …

Enantioselective organocatalysis

PI Dalko, L Moisan - Angewandte Chemie International Edition, 2001 - Wiley Online Library
The last few years have witnessed a spectacular advancement in new catalytic methods
based on metal‐free organic molecules. In many cases, these small compounds give rise to …

Reactions in micellar systems

T Dwars, E Paetzold, G Oehme - … Chemie International Edition, 2005 - Wiley Online Library
The notion of “green chemistry” has encouraged even synthetic organic chemists to include
water as a solvent. Incredible selectivities and activities can be achieved through the …

Enantioselective Kita oxidative spirolactonization catalyzed by in situ generated chiral hypervalent iodine (III) species

M Uyanik, T Yasui, K Ishihara - Angewandte Chemie International Edition, 2010 - infona.pl
The iodines (III) have it: The rational design of a conformationally flexible C 2‐symmetric
iodosylarene catalyst has been used for the enantioselective Kita oxidative …

Enantioselective synthesis of sulfoxides: 2000− 2009

E Wojaczynska, J Wojaczynski - Chemical reviews, 2010 - ACS Publications
In the field of asymmetric synthesis, nonracemic sulfoxides are recognized as valuable and
efficient reagents. Their extensive use as chiral auxiliaries and intermediates is …

Asymmetric dearomatizing spirolactonization of naphthols catalyzed by spirobiindane-based chiral hypervalent iodine species

T Dohi, N Takenaga, T Nakae, Y Toyoda… - Journal of the …, 2013 - ACS Publications
This report details the development of a spirobiindane-based chiral hypervalent iodine
reagent, especially focusing on its structural elucidation for effective asymmetric induction of …

A chiral hypervalent iodine (III) reagent for enantioselective dearomatization of phenols

T Dohi, A Maruyama, N Takenaga… - Angewandte …, 2008 - Wiley Online Library
Asymmetric induction by hypervalent iodine reagent control is challenging work. Many
efforts have been devoted to the design of new chiral reagents with the aim of achieving …

Hypervalent iodine reagents as a new entrance to organocatalysts

T Dohi, Y Kita - Chemical communications, 2009 - pubs.rsc.org
The catalytic utilization of hypervalent iodine reagents, largely in consideration of
economical and environmental viewpoints, is a most attractive strategy due to their unique …