The Current Understanding of Mechanistic Pathways in Zeolite Crystallization

AJ Mallette, K Shilpa, JD Rimer - Chemical Reviews, 2024 - ACS Publications
Zeolite catalysts and adsorbents have been an integral part of many commercial processes
and are projected to play a significant role in emerging technologies to address the …

Unified mechanistic interpretation of amine-assisted silica synthesis methods to enable design of more complex materials

JRH Manning, C Brambila… - Molecular Systems Design …, 2021 - pubs.rsc.org
The design of porous sol–gel silica materials is a thriving research field, owing to silica's
diversity of properties and potential applications. Using a variety of additives, most …

Impact of a polymer modifier on directing the non-classical crystallization pathway of TS-1 zeolite: accelerating nucleation and enriching active sites

J Zhang, R Bai, Y Zhou, Z Chen, P Zhang, J Li… - Chemical Science, 2022 - pubs.rsc.org
The crystallization process directly affects the physicochemical properties and active centers
of zeolites; however, controllable tuning of the zeolite crystallization process remains a …

Regulating nonclassical pathways of silicalite‐1 crystallization through controlled evolution of amorphous precursors

MK Choudhary, M Kumar… - Angewandte Chemie …, 2019 - Wiley Online Library
Differentiating mechanisms of zeolite crystallization is challenging owing to the vast number
of species in growth solutions. The presence of amorphous colloidal particles is ubiquitous …

Cooperative effects of inorganic and organic structure-directing agents in ZSM-5 crystallization

A Chawla, R Li, R Jain, RJ Clark, JG Sutjianto… - … Systems Design & …, 2018 - pubs.rsc.org
Zeolite crystallization occurs in the presence of inorganic and/or organic structure-directing
agents (SDAs) that facilitate the formation of microporous crystals with various pore …

Nonionic polymer and amino acid-assisted synthesis of ZSM-5 nanocrystals and their catalytic application in the alkylation of 2-methylnaphthalene

J Zhan, Y Wang, T He, L Sheng, B Wu, Q Liu… - Dalton …, 2024 - pubs.rsc.org
The synthesis of nanosized ZSM-5 zeolites with high crystallinity and suitable acidity is very
significant for their great potential in various catalytic applications. Herein, a series of zeolite …

Molecular Modification of Zeolites with Cold Atmospheric-Pressure Plasma Jet: A Green and Facile Strategy

J Batur, Z Duan, M Jiang, R Li, Y Xie, XF Yu… - Chemistry of …, 2023 - ACS Publications
Widespread applications of zeolites demand the optimization of crystal size and
morphology. Crystal growth modifiers (CGMs) have been proved effective for zeolite rational …

Molecular modifiers suppress nonclassical pathways of zeolite crystallization

W Qin, A Agarwal, MK Choudhary, JC Palmer… - Chemistry of …, 2019 - ACS Publications
There has been significant interest in the area of zeolite synthesis, and more broadly in the
development of microporous catalysts, to establish methods of reducing crystal size. A …

Manipulation of amorphous precursors to enhance zeolite nucleation

D Parmar, Z Niu, Y Liang, H Dai, JD Rimer - Faraday Discussions, 2022 - pubs.rsc.org
Crystallization in media comprised of amorphous precursors is becoming a more common
phenomenon for numerous synthetic, biological, and natural materials that grow by a …

Cost-effective synthesis of CHA zeolites with controllable morphology and size

Y Guo, T Sun, X Liu, Q Ke, X Wei, Y Gu… - Chemical Engineering …, 2019 - Elsevier
Cost-effectively develop zeolites with controllable morphology and size is significant in
design and optimization of the physical properties for CO 2/CH 4 adsorption separation …