Two-dimensional electronic spectroscopy

E Fresch, FVA Camargo, Q Shen, CC Bellora… - Nature Reviews …, 2023 - nature.com
Two-dimensional electronic spectroscopy (2DES) is a popular technique that can track
ultrafast coherent and incoherent processes in real time. Since its development in the late …

Global analysis of coherence and population dynamics in 2D electronic spectroscopy

A Volpato, L Bolzonello, E Meneghin, E Collini - Optics express, 2016 - opg.optica.org
2D electronic spectroscopy is a widely exploited tool to study excited state dynamics. A high
density of information is enclosed in 2D spectra. A crucial challenge is to objectively …

Slow intramolecular vibrational relaxation leads to long-lived excited-state wavepackets

SR Rather, GD Scholes - The Journal of Physical Chemistry A, 2016 - ACS Publications
Broadband optical pump and compressed white light continuum probe were used to
measure the transient excited-state absorption, ground-state bleach, and stimulated …

Coherence in carotenoid-to-chlorophyll energy transfer

E Meneghin, A Volpato, L Cupellini… - Nature …, 2018 - nature.com
The subtle details of the mechanism of energy flow from carotenoids to chlorophylls in
biological light-harvesting complexes are still not fully understood, especially in the ultrafast …

Signatures of exciton dynamics and interaction in coherently and fluorescence-detected four-and six-wave-mixing two-dimensional electronic spectroscopy

P Malý, S Mueller, J Lüttig, C Lambert… - The Journal of Chemical …, 2020 - pubs.aip.org
Two-dimensional electronic spectroscopy (2DES) can be realized in increasing nonlinear
orders of interaction with the electric field, bringing new information about single-and multi …

Exciton-vibrational resonance and dynamics of charge separation in the photosystem II reaction center

VI Novoderezhkin, E Romero, J Prior… - Physical Chemistry …, 2017 - pubs.rsc.org
The dynamics of charge separation in the photosystem II reaction center (PSII-RC) in the
presence of intramolecular vibrations with their frequency matching the energy gap between …

Time-frequency methods for coherent spectroscopy

A Volpato, E Collini - Optics Express, 2015 - opg.optica.org
Time-frequency decomposition techniques, borrowed from the signal-processing field, have
been adapted and applied to the analysis of 2D oscillating signals. While the Fourier …

Versatile setup for high-quality rephasing, non-rephasing, and double quantum 2D electronic spectroscopy

L Bolzonello, A Volpato, E Meneghin, E Collini - JOSA B, 2017 - opg.optica.org
Two-dimensional electronic spectroscopy based on passive phase stabilization methods is
now well known and widely employed worldwide. In the most recent fully non-collinear …

Observing vibrational wavepackets during an ultrafast electron transfer reaction

SR Rather, JC Dean, GD Scholes - The Journal of Physical …, 2015 - ACS Publications
Recent work has proposed that coherent effects impact ultrafast electron transfer reactions.
Here we report studies using broadband pump–probe and two-dimensional electronic …

UltraStat: Ultrafast Spectroscopy beyond the Fourier Limit Using Bayesian Inference

E Harel - The Journal of Physical Chemistry A, 2024 - ACS Publications
The discrete Fourier transform (dFT) plays a central role in many ultrafast experiments,
allowing the recovery of spectroscopic observables from time-domain measurements. In …