Currently, the chemistry of organofluorine compounds is a leading and rapidly developing
area of organic chemistry. Fluorine present in a molecule largely determines its specific …

This study investigated the catalytic behavior of NHC-X ligands (X= F, Cl, Br, I) in
cycloaddition reactions, focusing on both mononuclear and binuclear pathways. Using NCI …

The mechanism of the C–N cross-coupling reaction, catalyzed by palladium complexes with
N-heterocyclic carbene ligands (Pd/NHC), was evaluated in detail at the molecular and …

A series of novel (NHC) PdCl2-PR3 complexes were synthesized and fully characterized by
1H, 13C, 31P NMR and FT-IR spectroscopy. These complexes showed high catalytic activity …

Pd/NHC complexes (NHCs–N-heterocyclic carbenes) with electron-withdrawing halogen
groups were prepared by developing an optimized synthetic procedure to access …

В настоящее время химия фторорганических соединений является одной из
лидирующих и быстро прогрессирующих областей органической химии. Наличие в …

To explore the high efficiency of the Buchwald–Hartwig amination with a wide substrate
scope, easily prepared and air stable palladium precatalysts bearing rigid hindered N …

Chloro‐/fluorobenzyl‐substituted benzimidazolium salts were synthesized from the reaction
of 4‐fluorobenzyl/2‐chloro‐4‐fluorobenzyl‐substituted benzimidazole and chlorinated …

A highly efficient and environmentally benign protocol for copper‐catalyzed alkyne–azide
cycloaddition (CuAAC) in industrially important alkane solvents was developed. New copper …

A series of heteroleptic cyclometallated 1, 2, 3-triazol-5-ylidene Ir III complexes were
synthesized and structurally characterized. These new complexes demonstrated …