Asymmetric catalysis using metal-organic frameworks

DN Dybtsev, KP Bryliakov - Coordination Chemistry Reviews, 2021 - Elsevier
To date, porous coordination polymers (metal–organic frameworks, MOFs) have been
extensively studied in multiple applications, including the use of homohiral or chirally …

Heterogenization of molecular catalysts within porous solids: the case of Ni-catalyzed ethylene oligomerization from zeolites to metal–organic frameworks

R Rajapaksha, P Samanta, EA Quadrelli… - Chemical Society …, 2023 - pubs.rsc.org
The last decade has seen a tremendous expansion of the field of heterogenized molecular
catalysis, especially with the growing interest in metal–organic frameworks and related …

Amino acid‐functionalized metal‐organic frameworks for asymmetric base–metal catalysis

R Newar, N Akhtar, N Antil, A Kumar… - Angewandte Chemie …, 2021 - Wiley Online Library
We report a strategy to develop heterogeneous single‐site enantioselective catalysts based
on naturally occurring amino acids and earth‐abundant metals for eco‐friendly asymmetric …

Incorporation of homogeneous organometallic catalysts into metal–organic frameworks for advanced heterogenization: a review

S Kumar, B Mohan, Z Tao, H You, P Ren - Catalysis Science & …, 2021 - pubs.rsc.org
Catalysis is among the most promising and fascinating techniques used in various research
fields and industries. Heterogeneous catalysts have received more attention than …

Isoreticular Metal–Organic Frameworks Confined Mononuclear Ru-Hydrides Enable Highly Efficient Shape-Selective Hydrogenolysis of Polyolefins

M Chauhan, N Antil, B Rana, N Akhtar, C Thadhani… - JACS Au, 2023 - ACS Publications
Upcycling nonbiodegradable plastics such as polyolefins is paramount due to their ever-
increasing demand and landfills after usage. Catalytic hydrogenolysis is highly appealing to …

Heterogenized Molecular Rhodium Phosphine Catalysts within Metal–Organic Frameworks for Alkene Hydroformylation

P Samanta, A Solé-Daura, R Rajapaksha… - ACS …, 2023 - ACS Publications
Molecularly defined organometallic rhodium phosphine complexes were efficiently
heterogenized within a MOF structure without affecting neither their molecular nature nor …

Unravelling the molecular structure and confining environment of an organometallic catalyst heterogenized within amorphous porous polymers

R Jabbour, CW Ashling, TC Robinson… - Angewandte Chemie …, 2023 - Wiley Online Library
The catalytic activity of multifunctional, microporous materials is directly linked to the spatial
arrangement of their structural building blocks. Despite great achievements in the design …

Carbon support tuned electrocatalytic activity of a single-site metal–organic framework toward the oxygen reduction reaction

W Ma, F Wu, P Yu, L Mao - Chemical science, 2021 - pubs.rsc.org
Metal–organic frameworks (MOFs) possess fantastic features such as structural diversity,
tunable accessible pores and atomically dispersed active sites, holding tremendous …

N-Formylation of amines utilizing CO 2 by a heterogeneous metal–organic framework supported single-site cobalt catalyst

R Newar, R Kalita, N Akhtar, N Antil… - Catalysis Science & …, 2022 - pubs.rsc.org
Catalytic N-formylation of amines using CO2 is considered pivotal for the sustainable
synthesis of formamides, key chemical feedstocks for synthesizing heterocycles …

Heterogenization of a Molecular Ni Catalyst within a Porous Macroligand for the Direct C–H Arylation of Heteroarenes

Y Mohr, M Alves-Favaro, R Rajapaksha, G Hisler… - ACS …, 2021 - ACS Publications
Direct C–H functionalization catalyzed by a robust and recyclable heterogeneous catalyst is
highly desirable for sustainable fine chemical synthesis. Bipyridine units covalently …