Chemical pressure in functional materials

K Lin, Q Li, R Yu, J Chen, JP Attfield… - Chemical Society Reviews, 2022 - pubs.rsc.org
Chemical pressure, a strange but familiar concept, is a lattice internal force caused by lattice
strain with chemical modifications and arouses great interest due to its diversity and …

Mechanistic Insights into C–C Coupling in Electrocatalytic CO2 Reduction Reaction

Y Hu, J Gong, H Zeb, H Lan, M Asif, H Xia… - Chemical …, 2024 - pubs.rsc.org
The utilization of CO2 has become an emerging area of research in response to climate
change and global warming. Electrochemical CO2 reduction reaction (CO2RR) holds …

Spin‐Crossover Grafted Monolayer of a Co (II) Terpyridine Derivative Functionalized with Carboxylic Acid Groups

V García‐López, N Giaconi, L Poggini… - Advanced Functional …, 2023 - Wiley Online Library
The synthesis and characterization of a new Co (II) spin‐crossover (SCO) complex based on
4′‐(4‐carboxyphenyl)− 2, 2′: 6′, 2 ″‐terpyridine ligand are reported. This complex can …

Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion

N Sakamoto, K Sekizawa, S Shirai, T Nonaka, T Arai… - Nature Catalysis, 2024 - nature.com
Molecular metal complex catalysts are highly tunable in terms of their CO2 reduction
performance by means of their flexible molecular design. However, metal complex catalysts …

Metal hydrogen-bonded organic frameworks: structure and performance

ZH Zhu, HL Wang, HH Zou, FP Liang - Dalton Transactions, 2020 - pubs.rsc.org
Although great progress has been made in the design, synthesis, and performance
expansion of porous materials, new porous materials with stable structures still need to be …

Charge manipulation in metal–organic frameworks: toward designer functional molecular materials

H Miyasaka - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
Multi-dimensional coordination frameworks whose charge states are controllable by the
sophisticated chemical modification of the components or by the application of stimuli are …

Light-induced excited spin state trapping in iron (III) complexes

M Nakaya, R Ohtani, LF Lindoy… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Spin crossover in iron (II) and iron (III) complexes continues to receive much attention for the
construction of molecular devices due to the presence of functionalities arising from their …

Water Molecule-Induced Reversible Magnetic Switching in a Bis-Terpyridine Cobalt (II) Complex Exhibiting Coexistence of Spin Crossover and Orbital Transition …

F Kobayashi, Y Komatsumaru, R Akiyoshi… - Inorganic …, 2020 - ACS Publications
The development of molecule-based switchable materials remains an important challenge
in the field of molecular science. Achievement of a structural phase transition induced by …

Tuning chain topologies and magnetic anisotropy in one-dimensional cobalt (II) coordination polymers via distinct dicarboxylates

Z Tian, S Moorthy, H Xiang, P Peng, M You, Q Zhang… - …, 2022 - pubs.rsc.org
Based on a terpyridine derivative and two different dicarboxylate ligands, two new cobalt (II)
coordination polymers, namely [Co (pytpy)(DClbdc)] n (1) and [Co (pytpy)(ndc)] n (2)(pytpy …

Hydrogen-bonded cobalt (II)-organic framework: normal and reverse spin-crossover behaviours

T Kanetomo, Z Ni, M Enomoto - Dalton Transactions, 2022 - pubs.rsc.org
A novel hydrogen-bonded metal-organic framework (H-MOF)[Co (HL) 2](DMF) 1.2 (H2O) 2.4
(1· solv), in which L= 2, 2′: 6′, 2′′-terpyridine-5, 5'-diyl biscarboxylate, was prepared …