We present an update and revision to our 2010 review on the topic of proton-coupled
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …

Recent advances in our mechanistic understanding of dye-sensitized electron transfer
reactions occurring at metal oxide interfaces are described. These advances were enabled …

The effect of proton transfer on water oxidation has hardly been measurably established in
heterogeneous electrocatalysts. Herein, two isomorphous manganese phosphates …

In photoelectrochemical (PEC) cells, selective oxidation of organic substrates coupled with
hydrogen evolution represents a promising approach for value-added chemical production …

The proton-coupled electron transfer (PCET) mechanism for the reaction Mox–OH+ e–+
H+→ Mred–OH2 was determined through the kinetic resolution of the independent electron …

High‐valent iron‐oxo species are appealing for conducting O− O bond formation for water
oxidation reactions. However, their high reactivity poses a great challenge to the dissection …

Metal nanoclusters (MNCs) represent a promising class of materials for catalytic carbon
dioxide and proton reduction as well as dihydrogen oxidation. In such reactions, multiple …

The total reorganization energy, λ, for interfacial electron transfer, ET, from a conductive
electrode to redox-active molecules at fixed positions within the electric double layer, EDL …

The reorganization energy (λ) for interfacial electron transfer (ET) and proton-coupled ET
(PCET) from a conductive metal oxide (In2O3: Sn, ITO) to a surface-bound water oxidation …

Despite numerous experimental and theoretical studies devoted to the oxygen evolution
reaction (OER), the mechanism of the OER on transition metal oxides remains controversial …