Decarboxylative reactions with and without light–a comparison

J Schwarz, B König - Green Chemistry, 2018 - pubs.rsc.org
Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …

Decarboxylation as the key step in C− C bond‐forming reactions

T Patra, D Maiti - Chemistry–A European Journal, 2017 - Wiley Online Library
C− C bond forming reactions incarnate the core of organic synthesis because of their
fundamental applications to molecular diversity and complexity. In recent years, use of …

Decarboxylative borylation and cross-coupling of (hetero) aryl acids enabled by copper charge transfer catalysis

NW Dow, PS Pedersen, TQ Chen… - Journal of the …, 2022 - ACS Publications
We report a copper-catalyzed strategy for arylboronic ester synthesis that exploits
photoinduced ligand-to-metal charge transfer (LMCT) to convert (hetero) aryl acids into aryl …

Recent advances in transition-metal-catalyzed functionalization of unstrained carbon–carbon bonds

F Chen, T Wang, N Jiao - Chemical Reviews, 2014 - ACS Publications
The carbon− carbon bond is the most widespread and fundamental bond existing in organic
compounds. The reaction of this kind of bond is almost ubiquitous in live activities and …

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

N Rodríguez, LJ Goossen - Chemical Society Reviews, 2011 - pubs.rsc.org
This critical review examines transition metal-catalyzed decarboxylative couplings that have
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …

Visible-light-driven carboxylation of aryl halides by the combined use of palladium and photoredox catalysts

K Shimomaki, K Murata, R Martin… - Journal of the American …, 2017 - ACS Publications
A highly useful, visible-light-driven carboxylation of aryl bromides and chlorides with CO2
was realized using a combination of Pd (OAc) 2 as a carboxylation catalyst and Ir (ppy) 2 …

Hydrodecarboxylation of carboxylic and malonic acid derivatives via organic photoredox catalysis: substrate scope and mechanistic insight

JD Griffin, MA Zeller, DA Nicewicz - Journal of the American …, 2015 - ACS Publications
A direct, catalytic hydrodecarboxylation of primary, secondary, and tertiary carboxylic acids
is reported. The catalytic system consists of a Fukuzumi acridinium photooxidant with …

Carboxylic acids as substrates in homogeneous catalysis

LJ Gooßen, N Rodríguez… - Angewandte Chemie …, 2008 - Wiley Online Library
In organic molecules carboxylic acid groups are among the most common functionalities.
Activated derivatives of carboxylic acids have long served as versatile connection points in …

Chemoselective Decarboxylative Protonation Enabled by Cooperative Earth‐Abundant Element Catalysis

YC Lu, JG West - Angewandte Chemie, 2023 - Wiley Online Library
Decarboxylative protonation is a general deletion tactic to replace polar carboxylic acid
groups with hydrogen or its isotope. Current methods rely on the pre‐activation of acids, non …

The use of carboxylic acids as traceless directing groups for regioselective C–H bond functionalisation

M Font, JM Quibell, GJP Perry, I Larrosa - Chemical Communications, 2017 - pubs.rsc.org
The ability to selectively functionalise a specific C–H bond is a long-standing challenge due
to the ubiquity of such bonds in organic molecules. One of the most common approaches to …