Fluoro-bridged rare-earth metal–organic frameworks

M Abbas, S Sheybani, ML Mortensen, KJ Balkus - Dalton Transactions, 2024 - pubs.rsc.org
Rare-earth (RE) metal–organic frameworks (MOFs) offer unique optical, electronic, and
magnetic properties. RE metals tend to make binuclear metal nodes resulting in dense …

Fabrication of ultrathin two-dimensional MOF nanosheets with cage-like cavities showing excellent adsorption for lead (II)

H Sun, KZ Wang, MR Yao, CX Yu, YH Song… - Inorganic Chemistry …, 2023 - pubs.rsc.org
In this work, we present a top-down method for the preparation of 2D MOF nanosheets with
cavity structures. The pro-ligand 25, 26, 27, 28-tetrakis [(carboxyl) methoxy] calix [4] arene …

Lanthanide Metal–Organic Frameworks Exhibiting Fluoro-Bridged Extended Chains: Synthesis, Crystal Structures, and Magnetic Properties

ML Mortensen, S Bisht, M Abbas, H Firouzi… - Inorganic …, 2023 - ACS Publications
Two fluoro-bridged lanthanide-containing metal–organic frameworks (MOFs) were
synthesized using 2, 2′-bipyridine-4, 4′-dicarboxylic acid (BPDC), a fluorinated …

Reverse modulation of defect density of Ce-MOF-808 by solvent-assisted ligand exchange for dicyclopentadiene hydrogenation

D Zhao, F Hu, R Li, X Xu, Z Wang, Z Xi, J Tong… - Science China …, 2025 - Springer
Defect engineering is a pivotal strategy for tailoring the electronic structure and
physicochemical properties of catalysts, yet the straightforward manipulation of defect …

A mixed polynuclear clusters-based Y-MOF with an unprecedented (12, 12, 18)-c topology: highly efficient propylene/ethylene separation and iodine adsorption

D Wang, Z Shi, W Li, G Li, X Liu, Y Liu - Chemical Engineering Journal, 2024 - Elsevier
The design and synthesis of highly stable metal–organic frameworks (MOFs) bearing
unpredictable polynuclear clusters and new topologies are important for the development of …

Encapsulation of cobaltocenium ions in a zeolite-like metal–organic framework

M Abbas, AM Marti, A Umer, M Joy, YC Yang… - New Journal of …, 2023 - pubs.rsc.org
The templating and structure-directing additives are well known for zeolites, but are less
common for metal–organic frameworks (MOFs). A cobaltocenium cation, Cp2Co+ (Cp …

Disorder and Sorption Preferences in a Highly Stable Fluoride-Containing Rare-Earth fcu-Type Metal–Organic Framework

ARBJ Lutton-Gething, BF Spencer… - Chemistry of …, 2024 - ACS Publications
Rare-earth (RE) metal–organic frameworks (MOFs) synthesized in the presence of fluorine-
donating modulators or linkers are an important new subset of functional MOFs. However …

Environmental concentrations of per/polyfluoroalkyl substances promote the conjugative transfer of antibiotic resistance genes

Z Xu, J Xiong, C Li, S Hu, Z Li, Y Ma, S Li… - Chemical Engineering …, 2024 - Elsevier
Per/polyfluoroalkyl substances (PFAS) are widespread in aquatic environments and pose
significant risks to human health. Their roles in the spread of antibiotic resistance genes …

Electrolyte design for high power dual-ion battery with graphite cathode for low temperature applications

Y Zhao, H Zhu, L Xing, YW Denis - Chemical Engineering Journal, 2024 - Elsevier
The design of electrolyte suitable for low-temperature use is of great significance to expand
the applications of energy storage devices. Dual-ion battery (DIB) with fast ion transport …

[HTML][HTML] Synthesis and Characterization of Highly Fluorinated Hydrophobic Rare–Earth Metal–Organic Frameworks (MOFs)

M Abbas, B Murari, S Sheybani, M Joy, KJ Balkus Jr - Materials, 2024 - mdpi.com
Tuning a material's hydrophobicity is desirable in several industrial applications, such as
hydrocarbon storage, separation, selective CO2 capture, oil spill cleanup, and water …