The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews …

Covering: 1973 to the end of 2013 The vinylogous Mukaiyama aldol reaction (VMAR) allows
efficient access to larger segments for complex natural product synthesis, primarily …

The vinylogous Mukaiyama aldol reaction (VMAR) is a powerful tool of polyketide synthesis,
which constructs a large size structure by simultaneous introduction of the stereogenic …

The commercial macrolide antibiotic fidaxomicin was synthesized in a highly convergent
manner. Salient features of this synthesis include a β-selective noviosylation, a β-selective …

Conspectus The construction of libraries of acyclic polyketides remains a challenging topic,
mostly due to the difficulties associated with finding the right balance between diversity and …

Two key reaction types were used for the total synthesis of the antibiotic agent (+)‐TMC‐
151C: the vinylogous Mukaiyama aldol reaction and silicon‐tethered ring‐closing …

Asymmetric total syntheses of nannocystins A and A0 were achieved in a convergent route
starting from simple materials. Nannocystin family natural products bear potent anticancer …

The Kobayashi aldol reaction has been used to construct anti-aldol products by remote
stereoinduction. Since the product of the Kobayashi aldol reaction has a typical polyketide …

The development of aqueous methods for generating enantiopure β-hydroxy carbonyl
compounds is an important goal because these subunits compose many bioactive …

The MIDA touch: A concise and highly convergent protecting‐group‐free total synthesis of
(−)‐myxalamide A involves a stereoselective vinylogous Mukaiyama aldol reaction of a …