In recent years, it has been demonstrated that amide carbon–nitrogen bonds can be
activated and selectively cleaved using transition metal catalysts. However, these …

Covers all the aspects of the recent achievements in silver catalyzed reactions Silver
catalysis has emerged as a powerful tool in the field of organic synthesis. This …

Quantum chemical calculations of nuclear magnetic resonance (NMR) shifts and coupling
constants have been extensively employed in recent years mainly to facilitate structural …

A one-pot gold-catalyzed hydroalkoxylation/Povarov reaction cascade of alkynols with N-
aryl imines or in situ generated iminium has been developed. The protocol provides a facile …

The convergent synthesis of a fully elaborated C13–C27 fragment of madeirolide A has
been achieved. The key features of the synthesis include the stereocontrolled construction of …

The mandelalides comprise a family of structurally complex marine macrolides that display
significant cytotoxicity against several human cancer cell lines. Presented here is a full …

A flexible synthetic method toward highly substituted tetrahydropyran is reported. The key
transformation involves atom-efficient sequential metal catalysis consisting of Pd-catalyzed …

Silver-catalyzed nucleophilic addition and intramolecular Friedel–Crafts alkylation between
α-oxoketene dithioacetals and tertiary propargylic carbonates have been realized. The …

Two new compounds namely, 6-methyl-1-(p-tolyl) hept‑3‑yne-1, 5-diol (1) and N-(5‑hydroxy-
1-phenylhex-3-yn-1-yl)-4-nitrobenzenesulfonamide (2) have been synthesized and …

Current synthesis of α-substituted 3, 6-dihydro-2H-pyrans dominantly relies on functional
group transformation. Herein, a direct and practical oxidative Csingle bondH alkynylation …