Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …

N-Heterocyclic carbenes (NHC) are nowadays ubiquitous and indispensable in many
research fields, and it is not possible to imagine modern transition metal and main group …

Phosphorus ylides are 1, 2-dipolar compounds with a negative charge on the carbon atom.
This charge is stabilized by the neighbouring onium moiety, but can also be shifted towards …

We report a combined experimental and theoretical study on the first examples of
carbodicarbene (CDC)‐stabilized bismuth complexes, which feature low‐coordinate cationic …

The long‐sought carbene–bismuthinidene,(CAAC) Bi (Ph), has been synthesized. Notably,
this represents both the first example of a carbene‐stabilized subvalent bismuth complex …

The BP unsaturated unit is a very attractive functional group as it provides novel reactivity
and unique physical properties. Nonetheless, applications remain limited so far due to the …

Herein, the synthesis of new low‐valent Group 14 phosphinidenide complexes [({SIDipp} P)
2m] exhibiting P–M pπ–pπ interactions (SIDipp= 1, 3‐bis (2, 6‐diisopropylphenyl) …

The reactions of the N-heterocyclic carbene-phosphinidene adducts (NHC) PSiMe3 and
(NHC) PH with the dinuclear ruthenium and osmium complexes [(η6-p-cymene) MCl2] 2 (M …

The cyclic alkyl (amino) carbene (cAAC) anchored silylene with two phosphinidenes was
isolated as (cAAC) Si {P (cAAC)} 2 (3) at room temperature, which was synthesized from the …

The reaction of the phosphorus and arsenic dihalides (WCA-IDipp) ECl2 (E= P, As) that bear
an anionic N-heterocyclic carbene ligand with a weakly coordinating borate moiety (WCA= B …