Criegee intermediates and their impacts on the troposphere
Criegee intermediates (CIs), carbonyl oxides formed in ozonolysis of alkenes, play key roles
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
Criegee intermediates: production, detection and reactivity
In the context of tropospheric chemistry, Criegee intermediates denote carbonyl oxides with
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
Atmospheric chemistry of Criegee intermediates: Unimolecular reactions and reactions with water
Criegee intermediates are produced in the ozonolysis of unsaturated hydrocarbons in the
troposphere, and understanding their fate is a prerequisite to modeling climate-controlling …
troposphere, and understanding their fate is a prerequisite to modeling climate-controlling …
Water Charge Transfer Accelerates Criegee Intermediate Reaction with H2O– Radical Anion at the Aqueous Interface
Criegee intermediates (CIs) are important carbonyl oxides that may react with atmospheric
trace chemicals and impact the global climate. The CI reaction with water has been widely …
trace chemicals and impact the global climate. The CI reaction with water has been widely …
Unimolecular decay strongly limits the atmospheric impact of Criegee intermediates
Stabilized Criegee intermediates (SCI) are reactive oxygenated species formed in the
ozonolysis of hydrocarbons. Their chemistry could influence the oxidative capacity of the …
ozonolysis of hydrocarbons. Their chemistry could influence the oxidative capacity of the …
Four-carbon Criegee intermediate from isoprene ozonolysis: Methyl vinyl ketone oxide synthesis, infrared spectrum, and OH production
The reaction of ozone with isoprene, one of the most abundant volatile organic compounds
in the atmosphere, produces three distinct carbonyl oxide species (RR′ COO) known as …
in the atmosphere, produces three distinct carbonyl oxide species (RR′ COO) known as …
Atmospheric kinetics: bimolecular reactions of carbonyl oxide by a triple-level strategy
Criegee intermediates in the atmosphere serve as oxidizing agents to initiate aerosol
formation, which are particularly important for atmospheric modeling, and understanding …
formation, which are particularly important for atmospheric modeling, and understanding …
Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate
RL Caravan, MF Vansco, K Au… - Proceedings of the …, 2020 - National Acad Sciences
Isoprene has the highest emission into Earth's atmosphere of any nonmethane hydrocarbon.
Atmospheric processing of alkenes, including isoprene, via ozonolysis leads to the formation …
Atmospheric processing of alkenes, including isoprene, via ozonolysis leads to the formation …
Structure-dependent reactivity of Criegee intermediates studied with spectroscopic methods
W Chao - Chemical Society Reviews, 2017 - pubs.rsc.org
Criegee intermediates are very reactive carbonyl oxides that are formed in reactions of
unsaturated hydrocarbons with ozone (ozonolysis). Recently, Criegee intermediates have …
unsaturated hydrocarbons with ozone (ozonolysis). Recently, Criegee intermediates have …
Criegee intermediates: What direct production and detection can teach us about reactions of carbonyl oxides
CA Taatjes - Annual Review of Physical Chemistry, 2017 - annualreviews.org
The carbonyl oxide intermediates in the ozonolysis of alkenes, often known as Criegee
intermediates, are potentially important reactants in Earth's atmosphere. For decades …
intermediates, are potentially important reactants in Earth's atmosphere. For decades …