An approach for the preparation and stabilization of primary phosphine oxides is presented
complementing previous methods of in situ generation. Specifically, RP (O) H2 where R …

Phosphanylidenephosphoranes of the type R–P (PR′ 3), also known as phospha-Wittig
reagents, can be utilized in a variety of bond activation reactions exploiting their …

This contribution reports the synthesis of two phosphinoferrocene ligands desymmetrized by
an inserted methylene spacer, viz., a bis-phosphine combining primary and tertiary …

A general approach for increasing the air‐stability of various primary phosphines in the
absence of kinetic stabilization is presented that contrasts with previous interpretations …

Phosphanylferrocene chalcogenides remain long overshadowed by their more common and
very successful phosphane counterparts. However, they also exhibit unique coordination …

Abstract α‐Functionalized phosphorus compounds are an important class of biologically
relevant molecules. The synthesis of these compounds often proceeds through the …

Organophosphorus compounds with stereogenic phosphorus and carbon atoms have
received increasing attention. In this regards, primary phosphines with a stereogenic carbon …

Reactivity of primary phosphines with two stoichiometric equivalents of imine results in the
formation of bis‐α‐aminophosphines (2 a–e), which can be subsequently oxidized in the …

The functionalization of (R, R)-S, S′-di-tert-butylferrocene-1, 1′-disulfoxide by
deprotolithiation-electrophilic trapping sequences was studied towards polysubstituted …

The reaction of [RuHCl (CO) L 3](L= PPh 3) with cyclohexylphosphine (PH 2 Cy) affords
[RuHCl (CO) L 2 (PH 2 Cy)], protonation of which in acetonitrile with HX affords [RuCl …