Metal-catalyzed highly Markovnikov-type selective hydrofunctionalization of terminal alkynes
provides a straightforward and atom-economical route to access 1, 1-disubstituted alkenes …

An important strategy for the efficient generation of diversity in molecular structures is the
utilization of common starting materials in chemodivergent transformations. The most …

Precise modification of a chemical site in a molecule at the single-atom level is one of the
most elegant yet difficult transformations in chemistry. A reagent specifically designed for …

Trimethylsilyl (TMS)‐protected alkynes served as selective alkyne cross‐coupling partners
in titanium‐catalyzed [2+ 2+ 1] pyrrole synthesis. Reactions of TMS‐protected alkynes with …

A cooperative catalyst system involving a Pd (0)/Senphos complex, tris (pentafluorophenyl)
borane, copper bromide, and an amine base, is demonstrated to catalyze trans …

Conjugated enynes are of great importance in organic synthesis, biochemistry and materials
sciences. The most commonly used synthetic methods include cross coupling reactions and …

A series of porous twofold interpenetrated In‐CoIII (porphyrin) metal–organic frameworks
(MOFs) were constructed by in situ metalation of porphyrin bridging ligands and used as …

Self-assembly of platinum (II) complexes to form supramolecular structures/nanostructures
due to intermolecular ligand π–π stacking and metal–ligand dispersive interactions is widely …

The Brønsted acid‐mediated reaction of unactivated alkynes with aryl sulfoxides leads to
simultaneous hydration and intermolecular C− C bond formation. This solvent‐and metal …

A neutral gold (I) complex [(IPr) AuCl](IPr= 1, 3-bis (diisopropylphenyl) imidazol-2-ylidene)
was found to be a highly effective catalyst for the hydration of terminal alkynes, including …