Revealing key structural features hidden in liquids and glasses

H Tanaka, H Tong, R Shi, J Russo - Nature Reviews Physics, 2019 - nature.com
A great success of solid state physics comes from the characterization of crystal structures in
the reciprocal (wave vector) space. The power of structural characterization in Fourier space …

Theory of the structural glass transition: A pedagogical review

V Lubchenko - Advances in Physics, 2015 - Taylor & Francis
The random first-order transition theory of the structural glass transition is reviewed in a
pedagogical fashion. The rigidity that emerges in crystals and glassy liquids is of the same …

[HTML][HTML] Communication: Experimentally determined profile of local glass transition temperature across a glassy-rubbery polymer interface with a Tg difference of 80 K

RR Baglay, CB Roth - The Journal of Chemical Physics, 2015 - pubs.aip.org
Studying the local glass transition temperature T g across a boundary, we investigate the
characteristic length scales of cooperative dynamics. High molecular weight polymers have …

Introduction to the colloidal glass transition

ER Weeks - 2017 - ACS Publications
Colloids are suspensions of small solid particles in a liquid and exhibit glassy behavior
when the particle concentration is high. In these samples, the particles are roughly …

Predicting how nanoconfinement changes the relaxation time of a supercooled liquid

TS Ingebrigtsen, JR Errington, TM Truskett, JC Dyre - Physical review letters, 2013 - APS
The properties of nanoconfined fluids can be strikingly different from those of bulk liquids. A
basic unanswered question is whether the equilibrium and dynamic consequences of …

Above, below, and in‐between the two glass transitions of ultrathin free‐standing polystyrene films: Thermal expansion coefficient and physical aging

JE Pye, CB Roth - Journal of Polymer Science Part B: Polymer …, 2015 - Wiley Online Library
In previous work we observed two simultaneous transitions in high molecular weight (MW)
free‐standing polystyrene films that were interpreted as two thickness‐dependent reduced …

[HTML][HTML] Thermodynamics, formation dynamics, and structural correlations in the bulk amorphous phase of the phase-field crystal model

S Abdalla, AJ Archer, L Gránásy, GI Tóth - The Journal of Chemical …, 2022 - pubs.aip.org
We investigate bulk thermodynamic and microscopic structural properties of amorphous
solids in the framework of the phase-field crystal (PFC) model. These are metastable states …

Distribution of diffusion constants and Stokes-Einstein violation in supercooled liquids

S Sengupta, S Karmakar - The Journal of chemical physics, 2014 - pubs.aip.org
It is widely believed that the breakdown of the Stokes-Einstein (SE) relation between the
translational diffusivity and the shear viscosity in supercooled liquids is due to the …

Structures and dynamics of glass-forming colloidal liquids under spherical confinement

B Zhang, X Cheng - Physical review letters, 2016 - APS
Recent theories predict that when a supercooled liquid approaches the glass transition,
particle clusters with a special “amorphous order” nucleate within the liquid, which lead to …

Boundary mobility controls glassiness in confined colloidal liquids

GL Hunter, KV Edmond, ER Weeks - Physical Review Letters, 2014 - APS
We use colloidal suspensions encapsulated in emulsion droplets to model confined glass-
forming liquids with tunable boundary mobility. We show that the dynamics in these …