Byproduct formation in heterogeneous catalytic ozonation processes

T Wu - Environmental Science: Advances, 2023 - pubs.rsc.org
Heterogeneous catalytic ozonation (HCO) is a promising advanced oxidation process (AOP)
that can effectively degrade recalcitrant organic pollutants. While research efforts have been …

Iodine oxidation by hydrogen peroxide in acidic solutions, Bray-Liebhafsky reaction and other related reactions

G Schmitz - Physical Chemistry Chemical Physics, 2010 - pubs.rsc.org
The kinetics of the iodine oxidation by hydrogen peroxide is a complicated function of the
concentrations of iodine, hydrogen peroxide, perchloric acid and iodate. A proposed model …

Malonic acid concentration as a control parameter in the kinetic analysis of the Belousov–Zhabotinsky reaction under batch conditions

SM Blagojević, SR Anić, ŽD Čupić, ND Pejić… - Physical Chemistry …, 2008 - pubs.rsc.org
The influence of the initial malonic acid concentration [MA] 0 (8.00× 10− 3≤[MA] 0≤ 4.30×
10− 2 mol dm− 3) in the presence of bromate (6.20× 10− 2 mol dm− 3), bromide (1.50× 10 …

Terpyridine-and Bipyridine-Based Ruthenium Complexes as Catalysts for the Belousov− Zhabotinsky Reaction

J Delgado, Y Zhang, B Xu… - The Journal of Physical …, 2011 - ACS Publications
We report the successful use of Ru (II)(terpy) 2 (1, terpy= 2, 2′: 6′, 2′′-terpyridine) as a
catalyst in the Belousov− Zhabotinsky (BZ) oscillating chemical reaction. We also examine …

Nonlinear response of a batch BZ oscillator to the addition of the anionic surfactant sodium dodecyl sulfate

L Sciascia, R Lombardo, MLT Liveri - The Journal of Physical …, 2007 - ACS Publications
The response of the Belousov− Zhabotinsy (BZ) system to the addition of increasing
amounts of the anionic surfactant sodium dodecyl sulfate (SDS) was monitored at 25.0° C in …

Investigation of the halogenate–hydrogen peroxide reactions using the electron paramagnetic resonance spin trapping technique

MC Pagnacco, MD Mojović… - The Journal of …, 2017 - ACS Publications
The differences in the mechanism of the halogenate reactions with the same
oxidizing/reducing agent, such as H2O2 contribute to the better understanding of versatile …

Mechanistic Investigations on the Belousov− Zhabotinsky Reaction with Oxalic Acid Substrate. 2. Measuring and Modeling the Oxalic Acid− Bromine Chain Reaction …

K Pelle, M Wittmann, K Lovrics… - The Journal of Physical …, 2004 - ACS Publications
The aim of the present paper is to study radical reactions important in the mechanism of the
Belousov− Zhabotinsky (BZ) reaction with its simplest organic substrate, oxalic acid, and to …

Thermodynamic and Kinetic Parameters of Cerium (IV) Complexes with Some Dicarboxylic Acids

OO Voskresenskaya, NA Skorik… - Russian Journal of …, 2018 - Springer
The thermodynamic and kinetic parameters of the cerium (IV) complexes formed in the initial
stage of oxidation of dicarboxylic acids (H 2 L), like pentanedioic, butanedioic, propanedioic …

Thermodynamics of the formation of intermediate complexes in the oxidation of oxalic acid by cerium (IV) and kinetics of their intramolecular redox decomposition

OO Voskresenskaya, NA Skorik - Russian Journal of Physical Chemistry A, 2015 - Springer
The thermodynamic and kinetic characteristics of the intermediate cerium (IV) oxalate
complex formed at the first stage of the oxidation of oxalic acid (H 2 Ox) by cerium (IV) are …

Uncatalyzed Reactions in the Classical Belousov− Zhabotinsky System. 2. The Malonic Acid− Bromate Reaction in Acidic Media

L Onel, G Bourceanu, I Bitter, M Wittmann… - The Journal of …, 2006 - ACS Publications
The title reaction was studied with various techniques in 1 M sulfuric acid, a usual medium
for the oscillatory Belousov− Zhabotinsky (BZ) reaction. It was found to be a more complex …