2D functionalized germananes: Synthesis and applications

S Ng, M Pumera - Advanced Materials, 2023 - Wiley Online Library
In the realm of 2D layered materials, the monoelemental group 14 Xene, germanene, as the
germanium analog of graphene, has emerged as the next prospective candidate. Preceded …

Giant enhancement of seebeck coefficient by deformation of silicene buckled structure in calcium‐intercalated layered silicene film

T Terada, Y Uematsu, T Ishibe… - Advanced Materials …, 2022 - Wiley Online Library
Layered silicene with deformed buckled structure attracts great interest as a next generation
2D Dirac thermoelectric material beyond conventional layered materials. However, the …

Edge-Hydrogenated Germanene by Electrochemical Decalcification-Exfoliation of CaGe2: Germanene-Enabled Vapor Sensor

E Kovalska, N Antonatos, J Luxa, Z Sofer - ACS nano, 2021 - ACS Publications
Two-dimensional germanene has been recently explored for applications in sensing,
catalysis, and energy storage. The potential of this van der Waals material lies in its …

Reaction Mechanism and Performance of Innovative 2D Germanane‐Silicane Alloys: SixGe1−xH Electrodes in Lithium‐Ion Batteries

S Wei, T Hartman, S Mourdikoudis, X Liu… - Advanced …, 2024 - Wiley Online Library
The adjustable structures and remarkable physicochemical properties of 2D monoelemental
materials, such as silicene and germanene, have attracted significant attention in recent …

Deciphering the Polymorphism of CaSi2: The Influence of Heat and Composition

XJ Feng, W Carrillo-Cabrera, A Ormeci… - Inorganic …, 2024 - ACS Publications
The Zintl phase CaSi2 is a layered compound with stacking variants known as 1P, 3R, and
6R. We extend the series by the 21R polytype formed by rapid cooling of the melt. The …

Thermoelectric power factor enhancement of calcium-intercalated layered silicene by introducing metastable phase

T Terada, T Ishibe, T Katayama, K Sato… - Applied Physics …, 2021 - iopscience.iop.org
It has been theoretically predicted that the thermoelectric properties of silicene can be
enhanced by deforming its atomic structure. In CaSi 2, calcium-intercalated layered silicene …

Semimetal hR6-CaSi2 thin film: A transparent contact for Si optoelectronics

AV Shevlyagin, NG Galkin, KN Galkin… - Journal of Alloys and …, 2022 - Elsevier
Transparent conducting materials (TCMs) provide low cost and effective solution for the
modern optoelectronics. However, simultaneous high electrical conductivity and optical …

Faster and Safer “In situ” Synthesis of Germanane and Silicane

Y Georgantas, T Giousis, FP Moissinac… - Small …, 2024 - Wiley Online Library
Abstract Germanane (GeH) and silicane (SiH), members of the Xanes family, have garnered
significant attention as 2D materials due to their diverse properties, which hold promise for …

Growth of metastable 2H-CaSi2 films on Si (111) substrates with ultrathin SiO2 films by solid phase epitaxy

K Oh-ishi, M Kojima, T Yoshizaki… - Applied Physics …, 2023 - iopscience.iop.org
The Si-nano dot substrates formed using the ultrathin silicon oxide films were applied to
fabricate CaSi 2 films. The CaSi 2 formed by this process was identified as the metastable …

Synthesis and characterization of CaSi2 films for hydrogenated 2D Si nanosheets

R Takagaki, C Yamamoto, J Yamanaka… - Journal of Vacuum …, 2024 - pubs.aip.org
Hydrogenated two-dimensional (2D) Si nanosheet is a layered semiconductor synthesized
by topotactic conversion of CaSi 2 in HCl solution at low temperatures. The unavailability of …