Polyhalide-bonded metal complexes: Structural diversity in an eclectic class of compounds

SA Adonin, MN Sokolov, VP Fedin - Coordination Chemistry Reviews, 2018 - Elsevier
This review is focused on a special class of metal complexes where polyhalide units are
either coordinated to metal (“true polyhalide complexes”) or form specific associates with …

Supramolecular organometallic chemistry: the platinum (iv) paradigm

RJ Puddephatt - Dalton Transactions, 2022 - pubs.rsc.org
Supramolecular chemistry and the chemistry of alkyl derivatives of the transition metals are
both topics of considerable current interest, but the combination of the two fields is still …

Structurally-responsive ligands for high-performance catalysts

JM Blacquiere - ACS Catalysis, 2021 - ACS Publications
Hemilabile ligands that undergo reversible changes in denticity have long been exploited to
enable catalyst activation and to increase lifetime. However, this common description does …

Cycloneophylpalladium (IV) Complexes: Formation by Oxidative Addition and Selectivity of Their Reductive Elimination Reactions

A Behnia, M A. Fard, JM Blacquiere… - …, 2020 - ACS Publications
The cycloneophylpalladium (II) complexes [Pd (CH2CMe2C6H4)(κ2-N, N′-L)](L= RO
(CH2) 3N (CH2–2-C5H4N) 2, R= H, Me) undergo oxidation to Pd (IV) with bromine or iodine …

Synthesis, characterization and biological activity of new cyclometallated platinum (iv) iodido complexes

E Bauer, X Domingo, C Balcells, IH Polat… - Dalton …, 2017 - pubs.rsc.org
The synthesis of six novel cyclometallated platinum (IV) iodido complexes is accomplished
by intermolecular oxidative addition of methyl iodide (compounds 2a–2c) or iodine …

Platinum (II) and platinum (IV) complexes stabilized by abnormal/mesoionic C4-bound dicarbenes

V Khlebnikov, M Heckenroth, H Müller-Bunz… - Dalton …, 2013 - pubs.rsc.org
Platinum (II) complexes comprising abnormal diimidazolylidene ligands were synthesized
from cis-PtMe2 (DMSO) 2 using microwave-assisted double C–H bond activation. NMR …

Oxidation of Half-Lantern Pt2(II,II) Compounds by Halocarbons. Evidence of Dioxygen Insertion into a Pt(III)–CH3 Bond

V Sicilia, M Baya, P Borja, A Martín - Inorganic Chemistry, 2015 - ACS Publications
The half-lantern compound [{Pt (bzq)(μ-N^ S)} 2](1)[bzq= benzo [h] quinoline, HN^ S= 2-
mercaptopyrimidine (C4H3N2HS)] reacts with CH3I and haloforms CHX3 (X= Cl, Br, I) to …

Oxidative addition of halogens to a Cycloneophylplatinum (II) complex and evidence for C–H bond activation at Platinum (IV)

MA Fard, RJ Puddephatt - Journal of Organometallic Chemistry, 2020 - Elsevier
The reactions of halogens or their equivalent with the cycloneophylplatinum (II) complex [Pt
(CH 2 CMe 2 C 6 H 4)(phen*)], phen*= 3, 4, 7, 8-tetramethyl-1, 10-phenanthroline, are …

The history of organoplatinum chemistry in Iran: 40-year research

RB Aghakhanpour, S Paziresh… - Journal of the Iranian …, 2020 - Springer
This review article is based on the scientific investigations of Prof. Mehdi Rashidi during his
working years in Shiraz University, Chemistry Department, Organometallic Chemistry …

Platinum Elimination from Bis(triethylsilylpolyynyl) Complexes (n‐Bu2C(CH2PPh2)2)Pt((C≡C)nSiEt3)2 (n=2, 3) and Macrocycles Comprised of Four L2Pt …

BK Collins, JA Gladysz - Chemistry–A European Journal, 2024 - Wiley Online Library
The overarching goal of this study is to effect the elimination of platinum from adducts with
cis–C≡ C− Pt− C≡ C‐linkages, thereby generating novel conjugated polyynes. Thus, the …