Disproportionation and comproportionation reactions have become increasingly important
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …

The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Polypyridine-ligated nickel complexes are widely used as privileged catalysts in a variety of
cross-coupling reactions. The rapid adoption of these complexes is tentatively attributed to …

Driven by the inherent synthetic potential of CO2 as an abundant, inexpensive and
renewable C1 chemical feedstock, the recent years have witnessed renewed interest in …

Transformation of sterically hindered tertiary alkyl electrophiles under nickel-catalyzed
conditions to forge C (sp3)–C bonds and simultaneously create challenging all-carbon …

With the progressive increase in atmospheric CO2 over the years and owing to its potential
environmental threat, researchers have focused their attention on the fruitful utilization of …

We present a new, unified approach for the transformation of benzylic and allylic alcohols,
aldehydes, and ketones into boronic esters under electroreductive conditions. Key to our …

Metal-catalyzed regiodivergent reactions allow control over regioselectivity in the synthesis
of a wide range of organic products. Starting from the same material, it is possible to prepare …

A catalytic protocol that reliably predicts and controls the site-selective incorporation of CO2
to a wide range of unsaturated hydrocarbons utilizing water as formal hydride source is …

A mild, chemo-and site-selective catalytic protocol that allows for incorporating an alkylboron
fragment into unactivated olefins is described. The use of internal olefins enables C–C bond …