Symmetry strategies for high performance lanthanide-based single-molecule magnets

JL Liu, YC Chen, ML Tong - Chemical Society Reviews, 2018 - pubs.rsc.org
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …

Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

An air-stable Dy (III) single-ion magnet with high anisotropy barrier and blocking temperature

SK Gupta, T Rajeshkumar, G Rajaraman… - Chemical …, 2016 - pubs.rsc.org
Herein we report air-stable Dy (III) and Er (III) single-ion magnets (SIMs) with pseudo-D5h
symmetry, synthesized from a sterically encumbered phosphonamide, tBuPO (NHiPr) 2 …

Strategies toward high-temperature lanthanide-based single-molecule magnets

L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Magnetic relaxation pathways in lanthanide single-molecule magnets

RJ Blagg, L Ungur, F Tuna, J Speak, P Comar… - Nature …, 2013 - nature.com
Single-molecule magnets are compounds that exhibit magnetic bistability caused by an
energy barrier for the reversal of magnetization (relaxation). Lanthanide compounds are …

An electrostatic model for the determination of magnetic anisotropy in dysprosium complexes

NF Chilton, D Collison, EJL McInnes… - Nature …, 2013 - nature.com
Understanding the anisotropic electronic structure of lanthanide complexes is important in
areas as diverse as magnetic resonance imaging, luminescent cell labelling and quantum …

Molecule-based magnetic coolers

YZ Zheng, GJ Zhou, Z Zheng… - Chemical Society …, 2014 - pubs.rsc.org
There has been a rapid expansion in the use of molecular magnets for both low-and ultra
low-temperature cooling applications in recent years, and here we review the chemical …

[PDF][PDF] Magnetic anisotropy in a dysprosium/DOTA single‐molecule magnet: beyond simple magneto‐structural correlations

G Cucinotta, M Perfetti, J Luzon, M Etienne… - Angewandte Chemie …, 2012 - academia.edu
Lanthanides are strategic materials in current technology [1] and play a remarkable role in
magnetism thanks to their large magnetic moments and large anisotropy.[2] Molecular …