In the early 1990s, great excitement followed the discovery that a molecular transition metal coordination compound could, at liquid-helium temperatures, retain magnetization for long …
Herein we report air-stable Dy (III) and Er (III) single-ion magnets (SIMs) with pseudo-D5h symmetry, synthesized from a sterically encumbered phosphonamide, tBuPO (NHiPr) 2 …
Lanthanide-based single-molecule magnets are leading materials for achieving magnetization blocking at the level of one molecule. In this paper, we examine the physical …
P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of lanthanide coordination complexes, especially in the field of single molecule magnets …
K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in recent decades because of their potential advantages to create new single-molecule …
RJ Blagg, L Ungur, F Tuna, J Speak, P Comar… - Nature …, 2013 - nature.com
Single-molecule magnets are compounds that exhibit magnetic bistability caused by an energy barrier for the reversal of magnetization (relaxation). Lanthanide compounds are …
Understanding the anisotropic electronic structure of lanthanide complexes is important in areas as diverse as magnetic resonance imaging, luminescent cell labelling and quantum …
YZ Zheng, GJ Zhou, Z Zheng… - Chemical Society …, 2014 - pubs.rsc.org
There has been a rapid expansion in the use of molecular magnets for both low-and ultra low-temperature cooling applications in recent years, and here we review the chemical …
Lanthanides are strategic materials in current technology [1] and play a remarkable role in magnetism thanks to their large magnetic moments and large anisotropy.[2] Molecular …