Heteroatom-based diradical (oid) s

A Hinz, J Bresien, F Breher, A Schulz - Chemical Reviews, 2023 - ACS Publications
Heteroatom-centered diradical (oid) s have been in the focus of molecular main group
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …

NHCs in main group chemistry

V Nesterov, D Reiter, P Bag, P Frisch, R Holzner… - Chemical …, 2018 - ACS Publications
Since the discovery of the first stable N-heterocyclic carbene (NHC) in the beginning of the
1990s, these divalent carbon species have become a common and available class of …

Boron: its role in energy‐related processes and applications

Z Huang, S Wang, RD Dewhurst… - Angewandte Chemie …, 2020 - Wiley Online Library
Boron's unique position in the Periodic Table, that is, at the apex of the line separating
metals and nonmetals, makes it highly versatile in chemical reactions and applications …

Metallomimetic chemistry of boron

MA Légaré, C Pranckevicius, H Braunschweig - Chemical reviews, 2019 - ACS Publications
The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …

Frontiers in molecular p-block chemistry: From structure to reactivity

RL Melen - Science, 2019 - science.org
This year marks the 350th anniversary of the discovery of phosphorus by the alchemist
Hennig Brand. However, this element was not included in the p-block of the periodic table …

Advances in CO 2 activation by frustrated Lewis pairs: from stoichiometric to catalytic reactions

MN Khan, Y van Ingen, T Boruah, A McLauchlan… - Chemical …, 2023 - pubs.rsc.org
The rise of CO2 concentrations in the environment due to anthropogenic activities results in
global warming and threatens the future of humanity and biodiversity. To address excessive …

Main-group metallomimetics: transition metal-like photolytic CO substitution at boron

H Braunschweig, I Krummenacher… - Journal of the …, 2017 - ACS Publications
The carbon monoxide adduct of an unhindered and highly reactive CAAC-bound
arylborylene,[(CAAC) B (CO) Ar](CAAC= cyclic (alkyl)(amino) carbene), has been prepared …

Recent advances in the domain of cyclic (alkyl)(amino) carbenes

S Kumar Kushvaha, A Mishra… - Chemistry–An Asian …, 2022 - Wiley Online Library
Isolation of cyclic (alkyl) amino carbenes (cAACs) in 2005 has been a major achievement in
the field of stable carbenes due to their better electronic properties. cAACs and bicyclic …

Small molecule activation by boron-containing heterocycles

Y Su, R Kinjo - Chemical Society Reviews, 2019 - pubs.rsc.org
Most of the chemical and biological processes involving the fixation and transformation of
small molecules have long been exclusive for metal complexes. Meanwhile, the last …

Construction of Boron-Containing Aromatic Heterocycles

B Su, R Kinjo - Synthesis, 2017 - thieme-connect.com
Boron-containing aromatic systems exhibit unique electronic properties and reactivities that
have been extensively studied for a long time. This review highlights the recent …