Polymerization induced microphase separation for the fabrication of nanostructured materials

K Lee, N Corrigan, C Boyer - Angewandte Chemie, 2023 - Wiley Online Library
Polymerization induced microphase separation (PIMS) is a strategy used to develop unique
nanostructures with highly useful morphologies through the microphase separation of …

The emergence of reversible–deactivation radical polymerization in 3D printing

VA Bobrin, J Zhang, N Corrigan… - Advanced Materials …, 2023 - Wiley Online Library
The majority of materials 3D printed using vat photopolymerization techniques are prepared
by uncontrolled polymerization methods and cannot be easily modified to introduce …

Nano-to macro-scale control of 3D printed materials via polymerization induced microphase separation

VA Bobrin, Y Yao, X Shi, Y Xiu, J Zhang… - Nature …, 2022 - nature.com
Although 3D printing allows the macroscopic structure of objects to be easily controlled,
controlling the nanostructure of 3D printed materials has rarely been reported. Herein, we …

Nanostructure control in 3D printed materials

VA Bobrin, K Lee, J Zhang, N Corrigan… - Advanced …, 2022 - Wiley Online Library
Currently, there are no straightforward methods to 3D print materials with nanoscale control
over morphological and functional properties. Here, a novel approach for the fabrication of …

Polymerization-induced phase separation in rubber-toughened amine-cured epoxy resins: tuning morphology from the nano-to macro-scale

SC Leguizamon, J Powers, J Ahn, S Dickens… - …, 2021 - ACS Publications
Polymerization-induced phase separation enables fine control over thermoset network
morphologies, yielding heterogeneous structures with domain sizes tunable over 1–100 nm …

Polymerization induced microphase separation of ABC triblock copolymers for 3D printing nanostructured materials

X Shi, Y Yao, J Zhang, N Corrigan, C Boyer - Small, 2024 - Wiley Online Library
Polymerization‐induced microphase separation (PIMS) is a versatile technique for
producing nanostructured materials. In previous PIMS studies, the predominant approach …

Effect of Macromolecular Structure on Phase Separation Regime in 3D Printed Materials

Y Xiu, VA Bobrin, N Corrigan, J Zhang… - Macromolecular Rapid …, 2023 - Wiley Online Library
In this study, the fabrication of 3D‐printed polymer materials with controlled phase
separation using polymerization induced microphase separation (PIMS) via photoinduced …

Tailored mesoporous microspheres by polymerization-induced microphase separation in suspension

CH Peterson, JR Werber, HK Lee… - ACS Applied Polymer …, 2022 - ACS Publications
We describe the preparation of block polymer beads by aqueous suspension polymerization
to create poly (caprolactone)(PCL)-block-poly (styrene-co-divinylbenzene) beads that can …

Bicontinuous porous nanomaterials from block polymers radically cured in the disordered state for size-selective membrane applications

N Hampu, MW Bates, T Vidil… - ACS Applied Nano …, 2019 - ACS Publications
Solution-cast blends of lamellar-forming poly (styrene-stat-butadiene)-block-poly (lactide), P
(SsB)-b-PLA, and peroxide were heated above their effective order–disorder transition …

Nanostructure design of 3D printed materials through macromolecular architecture

D Wu, V Dev, VA Bobrin, K Lee, C Boyer - Chemical Science, 2024 - pubs.rsc.org
Polymerization-induced microphase separation (PIMS) has been previously combined with
3D printing to develop customized nanostructured materials with a wide range of functional …