Heterometallic CuII–LnIII complexes: Single molecule magnets and magnetic refrigerants

A Dey, P Bag, P Kalita, V Chandrasekhar - Coordination Chemistry …, 2021 - Elsevier
Molecular nanomagnets containing heterometallic 3d-4f complexes have been investigated
extensively for the past few years realizing the role of exchange interaction to minimize the …

Integrated CO2 capture and utilization: A priority research direction

FM Stuardi, F MacPherson, J Leclaire - Current opinion in green and …, 2019 - Elsevier
Carbon capture, utilization, and storage (CCUS), which has been proposed as a strategy to
mitigate greenhouse gas emissions and simultaneously offer alternative pathways of …

Modulating single-molecule magnet behavior towards multiple magnetic relaxation processes through structural variation in Dy 4 clusters

WM Wang, XM Kang, HY Shen, ZL Wu… - Inorganic Chemistry …, 2018 - pubs.rsc.org
Three Dy4 clusters,[Dy4 (tmhd) 8 (L) 2 (CH3OH) 2]· CH3OH (1),[Dy4 (hfac) 8 (L) 2 (DMF) 2]·
C7H16 (2) and [Dy4 (dbm) 6 (L) 2 (μ3-OH) 2]· CH2Cl2 (3)(tmhd= 2, 2, 6, 6-tetramethyl-3, 5 …

Self-assembly of octanuclear Ln (III)-based clusters: their large magnetocaloric effects and highly efficient conversion of CO 2

WM Wang, XY Xin, N Qiao, ZL Wu, L Li, JY Zou - Dalton Transactions, 2022 - pubs.rsc.org
The design and construction of high-nuclear lanthanide clusters with fascinating topology
and functional properties have been an active area of research, however, the development …

Molecular assemblies from linear-shaped Ln 4 clusters to Ln 8 clusters using different β-diketonates: disparate magnetocaloric effects and single-molecule magnet …

WM Wang, ZL Wu, JZ Cui - Dalton Transactions, 2021 - pubs.rsc.org
A series of tetranuclear lanthanide-based clusters [Ln4 (dbm) 6 (L) 2 (CH3OH) 4]· 2CH3OH
(Ln (III)= Gd (1), Dy (2), and Ho (3); H3L= 2-[(2-(hydroxyimino) propanehydrazide) methyl]-2 …

Enriching lanthanide single-ion magnetism through symmetry and axiality

SK Gupta, R Murugavel - Chemical Communications, 2018 - pubs.rsc.org
Rapidly growing modern information technology demands energy and cost efficient tools
that can efficiently store and process a large amount of data. However, the miniaturization …

A call to (green) arms: a rallying cry for green chemistry and engineering for CO 2 capture, utilisation and storage

J Leclaire, DJ Heldebrant - Green Chemistry, 2018 - pubs.rsc.org
Chemists, engineers, scientists, lend us your ears… Carbon capture, utilisation, and storage
(CCUS) is among the largest challenges on the horizon and we need your help. In this …

Lanthanide Contraction: What is Normal?

RB Jordan - Inorganic Chemistry, 2023 - ACS Publications
Renewed interest in lanthanide contraction results from its possible effect on the properties
and applications of Ln (III) compounds and the theory related to these issues. To understand …

Chemical tunnel-splitting-engineering in a dysprosium-based molecular nanomagnet

MA Sørensen, UB Hansen, M Perfetti… - Nature …, 2018 - nature.com
Total control over the electronic spin relaxation in molecular nanomagnets is the ultimate
goal in the design of new molecules with evermore realizable applications in spin-based …

Measurement of magnetic exchange in asymmetric lanthanide dimetallics: toward a transferable theoretical framework

MJ Giansiracusa, E Moreno-Pineda… - Journal of the …, 2018 - ACS Publications
Magnetic exchange interactions within the asymmetric dimetallic compounds [hqH2][Ln2
(hq) 4 (NO3) 3]· MeOH,(Ln= Er (III) and Yb (III), hqH= 8-hydroxyquinoline) have been directly …