Photoinduced structural dynamics of molecular systems mapped by time-resolved X-ray methods

M Chergui, E Collet - Chemical reviews, 2017 - ACS Publications
We review the tremendous advances in ultrafast X-ray science, over the past 15 years,
making the best use of new ultrashort X-ray sources including table-top or large-scale …

Using X-ray free-electron lasers for spectroscopy of molecular catalysts and metalloenzymes

U Bergmann, J Kern, RW Schoenlein, P Wernet… - Nature Reviews …, 2021 - nature.com
The metal centres in metalloenzymes and molecular catalysts are responsible for the
rearrangement of atoms and electrons during complex chemical reactions, and they enable …

Roadmap of ultrafast x-ray atomic and molecular physics

L Young, K Ueda, M Gühr… - Journal of Physics B …, 2018 - iopscience.iop.org
X-ray free-electron lasers (XFELs) and table-top sources of x-rays based upon high
harmonic generation (HHG) have revolutionized the field of ultrafast x-ray atomic and …

Short-wavelength free-electron laser sources and science: a review

EA Seddon, JA Clarke, DJ Dunning… - Reports on Progress …, 2017 - iopscience.iop.org
This review is focused on free-electron lasers (FELs) in the hard to soft x-ray regime. The
aim is to provide newcomers to the area with insights into: the basic physics of FELs, the …

2p x-ray absorption spectroscopy of 3d transition metal systems

FMF de Groot, H Elnaggar, F Frati, R Wang… - Journal of Electron …, 2021 - Elsevier
This review provides an overview of the different methods and computer codes that are used
to interpret 2p x-ray absorption spectra of 3d transition metal ions. We first introduce the …

Ferricyanide photo-aquation pathway revealed by combined femtosecond Kβ main line and valence-to-core x-ray emission spectroscopy

M Reinhard, A Gallo, M Guo, AT Garcia-Esparza… - Nature …, 2023 - nature.com
Reliably identifying short-lived chemical reaction intermediates is crucial to elucidate
reaction mechanisms but becomes particularly challenging when multiple transient species …

Theoretical Study of the Full Photosolvolysis Mechanism of [Ru(bpy)3]2+: Providing a General Mechanistic Roadmap for the Photochemistry of [Ru(N^N)3]2+-Type …

A Soupart, F Alary, JL Heully, PIP Elliott… - Inorganic …, 2020 - ACS Publications
A complete mechanistic picture for the photochemical release of bipyridine (bpy) from the
archetypal complex [Ru (bpy) 3] 2+ is presented for the first time following the description of …

Theoretical X‐ray spectroscopy of transition metal compounds

SI Bokarev, O Kühn - Wiley Interdisciplinary Reviews …, 2020 - Wiley Online Library
X‐ray spectroscopy is one of the most powerful tools to access structure and properties of
matter in different states of aggregation as it allows to trace atomic and molecular energy …

Perspective: Opportunities for ultrafast science at SwissFEL

R Abela, P Beaud, JA Van Bokhoven, M Chergui… - Structural …, 2017 - pubs.aip.org
We present the main specifications of the newly constructed Swiss Free Electron Laser,
SwissFEL, and explore its potential impact on ultrafast science. In light of recent …

Time-resolved X-ray spectroscopies of chemical systems: New perspectives

M Chergui - Structural Dynamics, 2016 - pubs.aip.org
The past 3–5 years have witnessed a dramatic increase in the number of time-resolved X-
ray spectroscopic studies, mainly driven by novel technical and methodological …