5-Hydroxymethylfurfural (HMF) in organic synthesis: a review of its recent applications towards fine chemicals

W Fan, C Verrier, Y Queneau… - Current organic …, 2019 - ingentaconnect.com
Background: 5-Hydroxymethylfurfural (5-HMF) is a biomass-derived platform chemical,
which can be produced from carbohydrates. In the past decades, 5-HMF has received …

Industrial Routes from Sugars and Biomass to CMF and Other 5‐(Halomethyl) furfurals

J Bueno Morón, F Arbore, GPM van Klink… - …, 2024 - Wiley Online Library
Abstract The synthesis of 5‐(halomethyl) furfurals (XMFs, X= F, Cl, Br, I), including 5‐
(chloromethyl) furfural (CMF), 5‐(bromomethyl) furfural (BMF), 5‐(iodomethyl) furfural (IMF) …

Sulfonated graphitic carbon nitride as a highly selective and efficient heterogeneous catalyst for the conversion of biomass-derived saccharides to 5 …

T Chhabra, A Bahuguna, SS Dhankhar… - Green …, 2019 - pubs.rsc.org
The catalytic conversion of biomass-derived chemicals to value added products is currently
a topic of high importance, as it addresses the problems pertaining to both energy and the …

Multigram synthesis of pure HMF and BHMF

G Trapasso, G Mazzi, B Chícharo… - … Process Research & …, 2022 - ACS Publications
5-Hydroxymethylfurfural (HMF) is a bio-based platform chemical that can be used as a
building block to produce several compounds with diverse applications. Even though HMF …

Taming the butterfly effect: modulating catalyst nanostructures for better selectivity control of the catalytic hydrogenation of biomass-derived furan platform chemicals

R Weng, X Lu, N Ji, A Fukuoka, A Shrotri, X Li… - Catalysis Science & …, 2021 - pubs.rsc.org
The metal-catalyzed hydrogenation of biomass-derived furan platform chemicals typically
represented by 5-hydroxymethylfurfural and furfural is a critical pathway for biomass …

The increasing value of biomass: moving from C6 carbohydrates to multifunctionalized building blocks via 5‐(hydroxymethyl) furfural

KI Galkin, VP Ananikov - ChemistryOpen, 2020 - Wiley Online Library
Recent decades have been marked by enormous progress in the field of synthesis and
chemistry of 5‐(hydroxymethyl) furfural (HMF), an important platform chemical widely …

Novel biobased furanic diols as potential alternatives to BPA: synthesis and endocrine activity screening

CA Sutton, A Polykarpov… - ACS Sustainable …, 2020 - ACS Publications
A series of asymmetric and symmetric diols were prepared in high yields from biomass-
derived feedstocks 5-hydroxymethyl furfural (HMF) and 2, 5-diformyl furan (DFF) as potential …

An easy scalable approach to HMF employing DMC as reaction media: reaction optimization and comparative environmental assessment

M Musolino, J Andraos, F Aricò - ChemistrySelect, 2018 - Wiley Online Library
In this work, bio‐based platform molecule 5‐hydroxymethylfurfural (HMF) was synthesised
under mild conditions (90° C) from D‐fructose using as media a mixture of dimethyl …

The Piancatelli rearrangement of non-symmetrical furan-2, 5-dicarbinols for the synthesis of highly functionalized cyclopentenones

F Cacheux, G Le Goff, J Ouazzani, J Bignon… - Organic Chemistry …, 2021 - pubs.rsc.org
Substituted and non-symmetrical furan-2, 5-dicarbinols were readily prepared from
hydroxymethylfurfural (HMF), a renewable raw material from biomass. The Piancatelli …

Beyond 2, 5-furandicarboxylic acid: status quo, environmental assessment, and blind spots of furanic monomers for bio-based polymers

M Annatelli, JS Velandia, G Mazzi, SV Pandeirada… - Green …, 2024 - pubs.rsc.org
Since 5-(hydroxymethyl) furfural (HMF) has been labelled as the “sleeping giant” of the bio-
based platform-chemical realm, numerous investigations have been devoted to the …