Pincers, tridentate ligands that prefer a meridional geometry, are a rising class because of
their distinctive combination of properties. They permit a good level of control on the nature …

Dihydrogen complexation with retention of the H–H bond, once an exotic concept, has by
now appeared in a very wide range of contexts. Three structural types are currently …

The thermodynamics and kinetics of all three cleavage modes for Rh–H, the transfer of H–,
H+, or H•, have been studied for the Rh (III) hydride complex Cp* Rh (2-(2-pyridyl) phenyl) H …

Radical reaction: A convenient synthesis of hydroxyl isoindolones by a Pd‐catalyzed C H
activation/annulation reaction with near “click chemistry” efficiency is presented (see …

Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are
synthesised and found to work as effective catalysts for the transformation of molecular …

A series of pincer complexes of Rh has been prepared and tested as catalysts for the
dimerization of terminal alkynes. The pincers included aryl/bis (phosphinite) POCOP, aryl/bis …

Lewis acid–transition metal (LA–TM) catalysts have been proven to have an advantage in
catalyzing hydrogen activation. Herein, a high-dimensional structure–activity relationship …

Abstract The κ2‐(P, N)− phosphine ligand precursor NH (CH2CH2PCy2) 2 can be used for
the synthesis of the rhodium (I) complex [Rh (CO){ĸ3‐(P, N, P)− Cy2PC2H4NHC2H4PCy2}] …

In recent years, metal complexes of pyridyl‐mesoionic carbene (MIC) ligands have been
reported as excellent homogeneous and molecular electrocatalysts. In combination with …

A neutral complex PN3P-Rh (I) Cl (2) was prepared from a reaction of the PN3P pincer
ligand (1) with [Rh (COD) Cl] 2 (COD= 1, 5-cyclooctadiene). Upon treatment with a suitable …